| Pd-TiO_2/C催化剂对甲酸的电催化氧化 |
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| 引用本文： | 张瑀珩,孙广超,耿绍文,谷庆阳,许伟锋,高颖,邬冰.Pd-TiO_2/C催化剂对甲酸的电催化氧化[J].化学工程师,2010(4):4-5,12. |
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| 作者姓名： | 张瑀珩 孙广超 耿绍文 谷庆阳 许伟锋 高颖 邬冰 |
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| 作者单位： | 1. 哈尔滨师范大学,化学化工学院,黑龙江,哈尔滨,150025
2. 大庆石油学院,华瑞学院,黑龙江,哈尔滨,150027 |
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| 基金项目： | 国家自然科学基金，黑龙江省自然科学基金，黑龙江省教育厅科学技术研究项目，哈尔滨市青年科学基金，哈尔滨师范大学博士启动基金，哈尔滨师范大学第四届大学生实践创新基金 |
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| 摘 要： | 用液相还原法制备Pd-TiO2/C催化剂。用循环伏安法(CV)和线性扫描法(LSV)考察了催化剂对甲酸的电催化氧化活性。通过计时电流曲线检测催化剂对甲酸的稳定性。结果表明Pd/TiO2/C催化剂中Pd粒子电化学比表面积增大,Pd-TiO2/C催化剂稳定,催化活性比Pd/C催化剂有较大幅度的提高。
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| 关 键 词： | 直接甲酸燃料电池 钯 二氧化钛 电催化氧化 |
Formic acid oxidation on Pd/TiO2/C catalyst |
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| ZHANG Yu-heng,SUN Guang-chao,GENG Shao-wen,GU Qing-yang,XU Wei-feng,GAO Ying,WU Bing.Formic acid oxidation on Pd/TiO2/C catalyst[J].Chemical Engineer,2010(4):4-5,12. |
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| Authors: | ZHANG Yu-heng SUN Guang-chao GENG Shao-wen GU Qing-yang XU Wei-feng GAO Ying WU Bing |
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| Affiliation: | 1.College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150080,China; 2. College of Huarui,Daqing Petroleum Institute,Harbin 150027,China) |
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| Abstract: | The carbon supported Pd/TiO2/C and Pd/C catalysts were prepared with liquid phase reduction method. The catalysts have been characterized by cyclic voltammetry （CV）, linear sweep vohammet.ry （LSV） and Amperometrie i-t techniques. It was found that the electrocatalystic activity of Pd/TiO2/C catalyst was higher than that of Pd/C catalyst for the synergistic effect of TiO2. This is also attributed to the larger electrochemical specific surface area of Pd/TiO2/C. |
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| Keywords: | direct formic acid fuel cell palladium titanium dioxide electrocatalytic-oxidation |
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