| 稀土元素钨钒锗（磷）杂多配合物热稳定性研究 |
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| 引用本文： | 马慧媛,李长云.稀土元素钨钒锗（磷）杂多配合物热稳定性研究[J].化学与粘合,1997(2):74-76,91. |
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| 作者姓名： | 马慧媛 李长云 |
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| 作者单位： | 哈尔滨师范大学化学系 |
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| 摘 要： | 合成了十八种Ｋｅｇｇｉｎ结构稀土元素四元杂多配合物Ｋ１２Ｈ３「Ｌｎ（ＧｅＷ１０ＶＯ３９）２」；ＸＨ２Ｏ和Ｋ１１Ｈ２「Ｌｎ（ＰＷ１０ＶＯ３９）２」．ＸＨ２Ｏ。利用ＴＧ－ＤＴＡ，变温红外光谱，变温Ｘ射线衍射和溶解性实验方法，对配合物的热稳定性进行了研究，讨论了影响热稳定性的因素。
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| 关 键 词： | 稀土 杂多配合物 热稳定性 钨 钒 锗 Keggin结构 |
Studies on Thermal Stability of Heteropoly Tungstovanadogermanate and Tungstovanadophosphate with Lanthanide |
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| Ma Huiyuan,Li Changyun,Shan Yongkui,Zhou Baibin and Zhou Hongli.Studies on Thermal Stability of Heteropoly Tungstovanadogermanate and Tungstovanadophosphate with Lanthanide[J].Chemistry and Adhesion,1997(2):74-76,91. |
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| Authors: | Ma Huiyuan Li Changyun Shan Yongkui Zhou Baibin and Zhou Hongli |
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| Abstract: | In this paper, eighteen heteropoly complexes of lanthanide with keggin structure have been synthesized. Their thermal stability was studied by TG-DTA, IR spectra, X-ray powder diffraction at various temperatures and solubility experimental method. The factors having influence on the thermal stability were studied. |
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| Keywords: | lanthanide heteropoly complex thermal stability |
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