| 聚酰亚胺-环氧树脂胶黏剂的固化动力学研究 |
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| 引用本文： | 许梅芳,毛蒋莉,虞鑫海,刘万章.聚酰亚胺-环氧树脂胶黏剂的固化动力学研究[J].化学与粘合,2011,33(2):17-20. |
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| 作者姓名： | 许梅芳 毛蒋莉 虞鑫海 刘万章 |
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| 作者单位： | 许梅芳,毛蒋莉,虞鑫海,XU Mei-fang,MAO Jiang-li,YU Xin-hai(东华大学应用化学系,上海,201620);刘万章,LIU Wan-zhang(浙江金鹏化工股份有限公司,浙江台州,318050) |
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| 摘 要： | 以2,2-双4-(4-氨基苯氧基)苯基1丙烷(BAPOPP)和2,2-双4-(3,4-二羧基苯氧基)苯基]丙烷二酐(BPADA)为原料在室温下于DMAe溶剂中合成了一种新型聚酰亚胺,并用其改性环氧树脂体系获得聚酰亚胺-环氧体系胶黏剂.利用差示扫描量热计(DSC),以不同的升温速率对聚酰亚胺-环氧树脂胶黏剂进行DSC...
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| 关 键 词： | 聚酰亚胺 环氧树脂 胶黏剂 固化反应 动力学 差热分析 |
Study on the Cure Reaction Kinetics of Polyimide-epoxy Resin Adhesive |
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| XU Mei-fang,MAO Jiang-li,YU Xin-hai , LIU Wan-zhang.Study on the Cure Reaction Kinetics of Polyimide-epoxy Resin Adhesive[J].Chemistry and Adhesion,2011,33(2):17-20. |
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| Authors: | XU Mei-fang MAO Jiang-li YU Xin-hai LIU Wan-zhang |
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| Affiliation: | XU Mei-fang1,MAO Jiang-li1,YU Xin-hai1 and LIU Wan-zhang2(1.Department of Applied Chemistry,Donghua University,Shanghai 201620,China,2.Zhejiang Golden ROC Chemical Co.,Ltd.,Taizhou 318050,China) |
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| Abstract: | The new type of polyimide powder was synthesized through the reactions of polycondensation of 2,2-bis4-(4-aminophenoxy)phenyl]propane(BAPOPP) and 2,2-bis4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride(BPADA) in DMAc solvent at room temperature and imidization by azeotropy.The novel polyimide-epoxy adhesive was also prepared by modification of epoxy resin with this polyimide.The DSC curves of the above-mentioned polyimide-epoxy adhesive were obtained with different heating rates.Moreover,the curing kine... |
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| Keywords: | Polyimide epoxy resin adhesive cure reaction kinetics DSC analysis |
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