Synthesis of a porphyrinic polymer for highly efficient oxidation of arylalkanes in water |
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| Affiliation: | 1. Polymer Materials Research Center, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, PR China;2. Department of Chemistry, Harbin University, Harbin, 150086, PR China;3. Department of Chemistry and Chemical Engineering, Shanxi Datong University, Datong 037009, PR China;4. Key Laboratory of Superlight Material and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin, 150001, PR China;1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, No. 135, Xingang Xi Road, Guangzhou, Guangdong, 510275, China;2. National Engineering Laboratory for VOCs Pollution Control Material & Technology, University of Chinese Academy of Sciences, Beijing, 100049, China;1. Institute of Solution Chemistry of the Russian Academy of Sciences, Ivanovo, 153045, Russia;2. Ivanovo State Power Engineering University, Ivanovo, 153003, Russia;3. Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia;1. Department of Physical Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran;2. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran |
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| Abstract: | A highly stable covalent-porphyrinic framework Mn-CPF-1 was synthesized by reaction of cyanuric chloride and tetraphenylamine porphyrin (TAPP) and subsequent metallation. Mn-CPF-1 exhibits remarkable catalytic activity and stability on catalytic oxidation of arylalkanes in water under mild conditions, which is much superior to the homogeneous analog Mn-tetraphenylporphyrin (Mn-TPP) under identical conditions. |
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