The interaction between co-polymer of vinylpyrrolidone and vinylacetate and anionic surfactants in aqueous solutions |
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Authors: | Kunio Esumi Tetsuya Maekawa |
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Affiliation: | (1) Department of Applied Chemistry and Institute of Colloid and Interface Science, Science University of Tokyo, Kagurazaka, Shinjuku-ku, 162 Tokyo, Japan |
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Abstract: | The interaction of co-polymers of vinylpyrrolidone-vinylacetate with anionic surfactants, such as lithium dodecyl sulfate
(LiDS), lithium perfluorooctane sulfonate (LiFOS) in aqueous solution, has been studied. When the content of vinylacetate
in the co-polymers increases, reduction in the surface tension of co-polymers alone becomes significant. In mixtures of co-polymers
and surfactants, co-polymer-LiFOS complexes are formed at lower surfactant concentration than that of co-polymer-LiDS. The
micropolarity of the co-polymers-surfactant complexes depends on the composition of co-polymers and is higher for co-polymer-LiFOS
than that for co-polymer-LiDS. Further, the solubilization behavior of α-(o-tolylazo-)-β-naphthylamine (Yellow OB) (Tokyo
Kasei Co., Ltd., Tokyo, Japan) in the co-polymer-surfactant complexes is almost independent of the co-polymer composition,
but different from the surfactants, where a very low solubilized amount of Yellow OB is observed for co-polymer-LiFOS. |
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Keywords: | Co-polymer of vinylpyrrolidone and vinylacetate co-polymer-surfactant complex fluorinated surfactant |
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