aDepartment of Chemical Engineering, Laval University, Sainte Foy, Canada G1K 7P4
bSiliCycle Inc., 1200 Ave. St-Jean-Baptiste, Suite 114, Quebec City, Canada G2E 5E8
Abstract:
Periodic mesostructured organosilicas (PMO) were first synthesized using 1,2-bis(triethoxysilyl)ethylene (BTENE) under acidic conditions using Pluronic 123 as surfactant. The ethylene bridges were then arylated with benzene using AlCl3 as catalyst. These materials were further treated with sulfuric acid for the sulfonation of the phenyl moieties yielding a new preparation of sulfonic acid functionalized PMO. Ordered hexagonal mesostructures with surface areas up to 440 m2/g and narrow pore size distribution (around 5.3 nm) were obtained. This work thus provides a new example of chemical modification for the conception of functionalized PMO catalysts. Liquid phase self-condensation of heptanal was performed at 75 °C in the presence of these catalysts and the results were compared with those obtained with several other heterogeneous acid catalysts.