| 六糠基六氮杂异伍兹烷的合成及其工艺的研究 |
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| 引用本文： | 侯安鑫,肖国民,吕建华,吴迎春.六糠基六氮杂异伍兹烷的合成及其工艺的研究[J].精细化工中间体,2007,37(1):46-49. |
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| 作者姓名： | 侯安鑫 肖国民 吕建华 吴迎春 |
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| 作者单位： | 东南大学,化学化工学院,江苏,南京,210096 |
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| 摘 要： | 通过用α-糠胺和乙二醛为原料合成了六糠基六氮杂异伍兹烷,对产物进行分离、提纯,目标产物的熔点为98.2～99.5℃。并通过正交实验法考察了温度、pH值、催化剂、时间等对产物收率的影响,确定了在温度为0～5℃、pH值为9～10、催化剂为高氯酸、时间为20h时产物的收率为42%。六糠基六氮杂异伍兹烷是一种新的具有六硝基六氮杂异伍兹烷(HNIW)构型的笼状前体,打破了过去只能用苄胺或取代苄胺来合成此前体的传统工艺,为两步法合成HNIW提供了有利的条件。即第一步HNIW笼状前体的合成,第二步前体的直接硝化合成HNIW。
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| 关 键 词： | HNIW 六糠基六氮杂异伍兹烷 六硝基六氮杂异伍兹烷 两步法 |
| 文章编号： | 1009-9212(2007)01-0046-04 |
| 修稿时间： | 2006-09-26 |
Synthesis of Hexafurfurylhexaazaisowurtzitane |
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| HOU An-xin,XIAO Guo-min,L Jian-hua,WU Ying-chun.Synthesis of Hexafurfurylhexaazaisowurtzitane[J].Fine Chemical Intermediates,2007,37(1):46-49. |
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| Authors: | HOU An-xin XIAO Guo-min L Jian-hua WU Ying-chun |
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| Affiliation: | College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, China |
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| Abstract: | Hexafurfurylhexaazaisowurtzitane,a new hexaazaisowurtzitane,is obtained by reaction of 2-aminomethylfuran and glyoxal. The product was separated,purified and identified by FT-IR and 1HNMR. Its melting point is 98.2~99.5℃ by measure. The effect of the temperature pH,catalyzer and time on the production yield is investigated by orthogonal experiment. The product yield is 42% in the optimal conditions such as 0～5℃, pH9～10, catalyzer perchloric acid and reaction time 20 h. This change the conception that hexaazaisowurtzitanes is limited solely to the condensation of certain benzylamines with glyoxal. The two-step synthesis processes for hexanitrohexaazaisowurtzitane are suggested including synthesis of hexsubstituted hexaazaisowurtzitane and synthesis of hexanitrohexaazaisowurtzitane by direct nitration |
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| Keywords: | HNIW hexafurfurylhexaazaisowurtzitane hexanitrohexaazaisowurtzitane 2-step process |
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