| 三嗪型紫外线吸收剂的合成及性能 |
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| 引用本文： | 昝帅,姜文凤,邵玉昌.三嗪型紫外线吸收剂的合成及性能[J].精细化工,2007,24(11):1106-1108. |
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| 作者姓名： | 昝帅 姜文凤 邵玉昌 |
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| 作者单位： | 1. 大连理工大学,化工学院,辽宁,大连,116023
2. 大连化工研究设计院,辽宁,大连,116023 |
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| 摘 要： | 用格氏试剂偶联法合成了4个有代表性的三嗪型紫外线吸收剂:2,4-双(2,4-二羟基苯基)-6-(4-甲氧基苯基)-1,3,5-三嗪、2,4-双(2,4-二羟基苯基)-6-苯基-1,3,5-三嗪、2-(2,4-二羟基苯基)-4,6-二苯基-1,3,5-三嗪和2,4,6-三(2,4-二羟基苯基)-1,3,5-三嗪,测定了它们的紫外光谱。其中,2,4-双(2,4-二羟基苯基)-6-(4-甲氧基苯基)-1,3,5-三嗪在UVB和UVA都有较强吸收,εmax=36000L/(mol.cm)(λmax=313nm),εmax=36333L/(mol.cm)(λmax=344nm),是其中最好的紫外线吸收剂。
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| 关 键 词： | 三嗪型紫外线吸收剂 紫外光谱 吸收强度 化妆品原料 |
| 文章编号： | 1003-5214（2007）11-1106-03 |
| 修稿时间： | 2007-04-10 |
The Synthesis and Ultraviolet Spectrum of s-Triazines UV Absorbers |
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| ZAN Shuai,JIANG Wen-feng,SHAO Yu-chang.The Synthesis and Ultraviolet Spectrum of s-Triazines UV Absorbers[J].Fine Chemicals,2007,24(11):1106-1108. |
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| Authors: | ZAN Shuai JIANG Wen-feng SHAO Yu-chang |
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| Abstract: | By Grignard reagent coupling,four s-triazine compounds were synthesized,namely 2,4-bis(2,4-dihydroxyphenyl)-6-(4-methoxyphenyl)-1,3,5-triazine,2,4-bis(2,4-dihydroxyphenyl)-6-phenyl-1,3,5-triazine,2-(2,4-dihydroxyphenyl)-4,6-diphenyl-1,3,5-triazine and 2,4,6-tri(2,4-dihydroxyphenyl)-1,3,5-triazine, and their ultraviolet spectra were measured.2,4-Bis(2,4-dihydroxyphenyl)-6-(4-methoxyphenyl)-1,3,5-triazine is the best UV absorber in four compounds. εmax=36 000 L/(mol·cm)(λmax=313 nm),εmax=36 333 L/(mol·cm)(λmax=344 nm)]. |
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| Keywords: | s-triazine UV absorber ultraviolet spectrum absorbance raw material of cosmetics |
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