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活性炭固载杂多酸催化合成柠檬酸三丁酯
引用本文:吴茂祥,高冬寿,李定,罗军华,王燕茗,马锦波,陈长章. 活性炭固载杂多酸催化合成柠檬酸三丁酯[J]. 精细化工, 1999, 16(4): 24-27
作者姓名:吴茂祥  高冬寿  李定  罗军华  王燕茗  马锦波  陈长章
作者单位:中国科学院福建物质结构研究所,应用化学研究室,福建,福州,350002
基金项目:福建省自然科学基金,中科院福建物构所发展基金
摘    要:用自制的固载杂多酸催化柠檬酸与正丁醇反应合成柠檬酸三丁酯。探讨了催化剂用量、反应时间、反应温度、酸醇比等因素对反应结果的影响。在酸醇的摩尔比为1∶6.5、催化剂的用量为柠檬酸质量的1%、反应温度145℃、反应时间3h的条件下,柠檬酸的酯化率可达97.4%。

关 键 词:增塑剂;柠檬酸三丁酯;酯化;杂多酸
文章编号:1003-5214(1999)04-0024-04

Catalytic Synthesis of Tri-butyl Citrate by a Activated Carbon Supported Heteropoly Acid
WU Mao-xiang,GAO Dong-shou,LI Ding,LUO Jun-hua,WANG Yan-ming,MA Jin-bo,CHEN Chang-zhang. Catalytic Synthesis of Tri-butyl Citrate by a Activated Carbon Supported Heteropoly Acid[J]. Fine Chemicals, 1999, 16(4): 24-27
Authors:WU Mao-xiang  GAO Dong-shou  LI Ding  LUO Jun-hua  WANG Yan-ming  MA Jin-bo  CHEN Chang-zhang
Abstract:A supported heteropoly acid catalyst has been prepared and was investigated for the esterification of n butanol with citric acid in the liquidsolid system.The effects of reaction conditions were investigated.The most suitable conditions for the reaction are as follows:acid alcohol ratio 16.5(mol),mass ratio of catalyst to acid 1.0%,reaction time 3h,reaction temperature 145.The experimental results showed that the supported heteropoly acid catalyst had high catalytic activity and stability.
Keywords:plasticizer  tributyl citrate  esterification  heteropoly acid
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