|
|||||
|
|
| 有机酸催化合成2,4,6,8,10,12-六苄基-2,4,6,8,10,12-六氮杂异伍兹烷 | |
| 引用本文： | 郑福平,欧育湘,陈江涛,陈博仁,周智明,叶玲,赵道慧.有机酸催化合成2,4,6,8,10,12-六苄基-2,4,6,8,10,12-六氮杂异伍兹烷[J].精细化工,2000,17(1):27-29. |
| 作者姓名： | 郑福平 欧育湘 陈江涛 陈博仁 周智明 叶玲 赵道慧 |
| 作者单位： | 1. 北京理工大学,化工与材料学院,北京,100081 2. 首都医科大学,基础医学院,北京,100054 3. 北京轻工业学院,化工系,北京,100037 |
| 基金项目： | 国防科工委预研基金!12060451867 |
| 摘 要： | 研究了十几种有机酸对合成２，４，６，８，１０，１２ 六苄基 ２，４，６，８，１０，１２ 六氮杂异伍兹烷（Ⅰ）的催化作用，每种催化剂均取得了较好催化效果。尤其是水杨酸和对甲苯磺酸，可分别使化合物Ⅰ的产率达到７５％ 和８２％ ～８４％ 。随对甲苯磺酸用量的增大，化合物Ⅰ的产率先增大后减小。 |
| 关 键 词： | 醛胺缩合 催化剂 2 4 6 8 10 12-六苄基-2 4 6 8 10 12-六氮杂异伍兹烷 |
| 文章编号： | 1003-5214(2000)01-0027-03 |
Preparation of 2,4,6,8,10,12-Hexabenzyl-2,4,6,8,10,12-hexaazaisowurtzitane Catalyzed by Organic Acids |
|
| ZHENG Fu-ping,OU Yu-xiang,CHEN Jiang-tao,CHEN Bo-ren,ZHOU Zhi-ming,YE Ling,ZHAO Dao-hui.Preparation of 2,4,6,8,10,12-Hexabenzyl-2,4,6,8,10,12-hexaazaisowurtzitane Catalyzed by Organic Acids[J].Fine Chemicals,2000,17(1):27-29. | |
| Authors: | ZHENG Fu-ping OU Yu-xiang CHEN Jiang-tao CHEN Bo-ren ZHOU Zhi-ming YE Ling ZHAO Dao-hui |
| Abstract: | To study the catalytic effect of organic acids on the preparation of 2,4,6,8,10,12 hexabenzyl 2,4,6,8,10,12 hexaazaisowurtzitane(Ⅰ) more than ten kinds of organic acids were tested. Every organic acid used showed good performance in the preparation of compound Ⅰ. The yields of compound Ⅰ reached 75% and 82%～84% respectively when using salicylic acid and p toluenesulfonic acid as catalysts. The yield of compound Ⅰ increased first and then decreased with increase of the amount of p toluenesulfonic acid. |
| Keywords: | aldehyde amine condensation catalyst 2 4 6 8 10 12 hexabenzyl 2 4 6 8 10 12 hexaazaisowurtzitane |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |