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DOC-Ⅰ降烯烃催化剂小型提升管反应性能评价
引用本文:贾春旭,赵如松,靳广洲,高俊斌,赵苗苗.DOC-Ⅰ降烯烃催化剂小型提升管反应性能评价[J].工业催化,2013,21(4):45-48.
作者姓名:贾春旭  赵如松  靳广洲  高俊斌  赵苗苗
作者单位:1.北京化工大学,北京 100029; 2.北京石油化工学院化工系,北京 102617
基金项目:国家重点基础研究发展计划(973计划)(2012CB215002)资助项目
摘    要:采用小型提升管催化裂化试验装置评价研制的DOC-Ⅰ降烯烃催化剂的催化裂化反应性能。结果表明,在反应温度500 ℃、剂油质量比6和停留时间1.99 s条件下,DOC-Ⅰ催化剂上原料油的转化率达75.01%,较参比催化剂提高1.79个百分点,相应的液化气产率降低0.28个百分点,汽油产率增加2.9个百分点,烯烃含量下降5.21个百分点,异构烷烃和芳烃含量明显增加,产品分布有效改善。表明研制的DOC-Ⅰ催化剂具有较好的催化裂化性能和降烯烃能力。

关 键 词:石油化学工程  提升管  催化裂化  DOC-Ⅰ催化剂  降烯烃  

Evaluation of catalitic cracking performance of DOC-Ⅰ catalyst for olefin reduction in a lab scale riser reactor
JIA Chunxu,ZHAO Rusong,JIN Guangzhou,GAO Junbin,ZHAO Miaomiao.Evaluation of catalitic cracking performance of DOC-Ⅰ catalyst for olefin reduction in a lab scale riser reactor[J].Industrial Catalysis,2013,21(4):45-48.
Authors:JIA Chunxu  ZHAO Rusong  JIN Guangzhou  GAO Junbin  ZHAO Miaomiao
Affiliation:1.Beijing University of Chemical Technology, Beijing 100029, China; 2.School of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
Abstract:The fluid catalytic cracking (FCC) performance of DOC-Ⅰ olefin reducing catalyst was evaluated in a lab scale riser reactor. The results showed that under the condition as follows: the ratio of catalyst to oil 6, reaction temperature 500 ℃ and reaction residence time 1.99 s,feed oil conversion over DOC-Ⅰ catalyst reached 75.01%,which was 1.79% higher than that over the reference catalyst.It was found that the content of olefins over DOC-Ⅰ catalyst reduced 5.21%,LPG yield declined 0.28%,gasoline yield increased 2.9%,the amount of isoparaffin and aromatic hydrocarbon increased significantly,and the desirable product distribution over DOC-Ⅰ catalyst was obtained compared with the reference catalyst.It was indicated that DOC-Ⅰ catalyst possessed ideal capability of FCC and olefin reduction.
Keywords:petrochemical technology  riser reactor  catalytic cracking  DOC-Ⅰ catalyst  olefin reduction  
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