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焙烧高岭土催化剂对催化甲醇制二甲醚性能的影响
引用本文:王鼎,刘丽娜. 焙烧高岭土催化剂对催化甲醇制二甲醚性能的影响[J]. 工业催化, 2021, 29(3): 69-72. DOI: 10.3969/j.issn.1008-1143.2021.03.010
作者姓名:王鼎  刘丽娜
作者单位:榆林职业技术学院化工学院,陕西 榆林719000;榆林学院化学与化工学院,陕西 榆林719000
基金项目:榆林市科技局项目(2019-113-02)
摘    要:为了考察高岭土焙烧前后性能的变化,将高岭土分别在200℃、400℃、600℃、和800℃进行焙烧,得到焙烧高岭土催化剂样品,并对催化剂进行TG-DTA、XRD和SEM等的分析及活性测试.结果表明,高岭土经过高温焙烧后转变为偏高岭土,高岭土的特征峰消失,同时孔道明显增多,甲醇转化率、二甲醚选择性和收率均提高.

关 键 词:催化剂工程  高岭土  焙烧  活性

Effect of roasting kaolin catalyst on methanolcatalytic conversion to dimethyl ether
Wang Ding,Liu Lina. Effect of roasting kaolin catalyst on methanolcatalytic conversion to dimethyl ether[J]. Industrial Catalysis, 2021, 29(3): 69-72. DOI: 10.3969/j.issn.1008-1143.2021.03.010
Authors:Wang Ding  Liu Lina
Affiliation:1. School of Chemical Engineering,Yulin Vocational And Technical College,Yulin 719000,Shaanxi,China;2. School of Chemistry and Chemical Engineering,Yulin University,Yulin 719000,Shaanxi,China
Abstract:In order to investigate the performance changes of kaolin before and after calcination,the kaolin was calcined at 200 ℃, 400 ℃, 600 ℃, and 800 ℃ respectively to obtain kaolin catalyst.The catalyst was characterized by TG-DTA,XRD,SEM, etc,and tested in methanol to dimethyl ether.The results showed that the kaolin was transformed into metakaolin after high-temperature roasting;The characteristic peaks of kaolin also disappeared;At the same time,the number of pores increased significantly;The methanol conversion, dimethyl ether selectivity and yield were all improved.
Keywords:catalyst engineering  kaolin  roasting  activity  
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