| 2,4-二羟基苯甲酸铜纳米催化剂的合成及性能 |
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| 引用本文： | 李裕,刘有智.2,4-二羟基苯甲酸铜纳米催化剂的合成及性能[J].工业催化,2007,15(6):66-68. |
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| 作者姓名： | 李裕 刘有智 |
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| 作者单位： | 1.太原理工大学化学化工学院，山西 太原 030024；2.中北大学化工与环境学院，山西 太原 030051 |
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| 基金项目： | 国家自然科学基金
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山西省自然科学基金 |
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| 摘 要： | 以2,4-二羟基苯甲酸和硫酸铜制备纳米燃速催化剂，采用TEM、XRD、TG和IR等手段对催化剂样品进行表征，考察了反应终点和反应浓度对收率的影响，洗涤溶剂极性影响最终催化剂形貌，实验表明,纳米催化剂对双基推进剂NC/NG热分解有明显催化效果。
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| 关 键 词： | 2 4-二羟基苯甲酸铜 反应沉淀法 纳米催化剂 |
| 文章编号： | 1008-1143（2007）06-0066-03 |
| 修稿时间： | 2007-01-02 |
Synthesis and properties of nanometer copper resorcylic catalyst |
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| LI Yu,LIU Youzhi.Synthesis and properties of nanometer copper resorcylic catalyst[J].Industrial Catalysis,2007,15(6):66-68. |
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| Authors: | LI Yu LIU Youzhi |
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| Affiliation: | 1.Institute of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024,Shanxi,China；2.Department of Chemical Engineering, North University of China, Taiyuan 030051,Shanxi,China |
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| Abstract: | Nanometer copper resorcylic catalyst was synthesized by reactive precipitation method. The samples obtained were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FTIR) and thermo gravimetric analyses (TG). The results indicated that a spherical resorcylic catalyst was obtained after treatment in ethanol solvent, and flake shape crystal after treatment in water solvent. Peak temperature for thermal decomposition of NC/NG decreased by 3 ℃, and decomposition enthalpy increased by 735 J·g－1.The catalyst hadremarkable catalytic effects in double base propellant NC/NG thermal decomposition. |
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| Keywords: | copper resorcylic catalyst reactive precipitation method nanometer catalyst |
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