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费托合成Fe基催化剂失活研究进展
引用本文:陈文迪,吕德义,郭中山,王峰,杨景麟,姚楠.费托合成Fe基催化剂失活研究进展[J].工业催化,2019,27(6):9-15.
作者姓名:陈文迪  吕德义  郭中山  王峰  杨景麟  姚楠
作者单位:浙江工业大学化学工程学院,工业催化研究所,浙江 杭州310014;神华宁夏煤业集团有限责任公司,宁夏 银川,750001
基金项目:国家重点研发计划项目《先进煤间接液化及产品加工成套技术开发》资助(2017YFB0602500)
摘    要:Fe基催化剂是具有工业化应用潜力的一种费托合成催化剂,但在反应中易因积炭、相变和烧结等原因失活,从而影响Fe基催化剂的实际应用。主要综述围绕上述3个引起铁基费托合成催化剂失活的主要原因所取得的研究进展。在此基础上,进一步探讨催化剂组成和预处理条件对Fe基催化剂的影响以及提高Fe基催化剂性能领域所取得的研究进展。

关 键 词:催化剂工程  费托合成  铁基催化剂  相变  积炭  烧结

Developments on deactivation of Fe-based Fischer-Tropsch synthesis catalysts
Chen Wendi,Lü,Deyi,Guo Zhongshan,Wang Feng,Yang Jinglin,Yao Nan.Developments on deactivation of Fe-based Fischer-Tropsch synthesis catalysts[J].Industrial Catalysis,2019,27(6):9-15.
Authors:Chen Wendi    Deyi  Guo Zhongshan  Wang Feng  Yang Jinglin  Yao Nan
Affiliation:1.Institute of Industrial Catalysis,College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310014,Zhejiang,China;2.Shenhua Ningxia Coal Industry Group Co.,Ltd.,Yinchuan 750411,Ningxia,China
Abstract:Fe-based catalyst is one of important Fischer-Tropsch synthesis catalysts with industrial application potential.However,Fe-based catalyst deactivates during the reaction owing to the carbon deposition,phase transformation and sintering,which influences the application of Fe-based catalysy.This paper reviewed the progress of above-mentioned deactivation reasons related to Fe-based catalyst.It also discussed effects of pretreatment conditions and chemical compositions of catalysts on the performances of Fe-based catalysts as well as the progress about how to improve Fe-based Fischer-Tropsch synthesis catalyst.
Keywords:catalyst engineering  Fischer-Tropsch synthesis  Fe-based catalyst  phase transformation  carbon deposition  sintering  
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