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一种合成4-甲氧基苯异氰酸酯的新方法
引用本文:劳旺梅,冯桂荣.一种合成4-甲氧基苯异氰酸酯的新方法[J].陶瓷研究与职业教育,2003,1(2):28-30.
作者姓名:劳旺梅  冯桂荣
作者单位:[1]唐山工业职业技术学院,河北唐山063020 [2]唐山师范学院化学系,河北唐山063000
摘    要:按Curtius重排反应原理,采用叠氮化钠与4-甲氧基苯甲酰氯反应合成4-甲氧基苯异氰酸酯。该法反应条件温和,操作简便,产率高。

关 键 词:Curtius重排反应  叠氮化钠  4-甲氧基苯异氰酸酯  合成

Synthesis of Aromatic Isocyanates by Curtius Rearrangement Reaction
LAO Wang-mei,FENG Gui-rong.Synthesis of Aromatic Isocyanates by Curtius Rearrangement Reaction[J].Ceramic Research and Vocational Education,2003,1(2):28-30.
Authors:LAO Wang-mei  FENG Gui-rong
Affiliation:LAO Wang-mei+1 FENG Gui-rong+2
Abstract:A new and simple method for the synthesis of aromatic isocyanates was developed by Curtius rearrangement reaction. The method here proposed has several advantages: manipulations are simple and reaction conditons are mild. The presence of water is completely avoided and yields in some instances are good.
Keywords:curtius rearrangement reaction  sodium azide  aromatic isocyanates  synthesis  
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