| 多硝基吡啶类化合物的合成及应用研究进展 |
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| 引用本文： | 王琼,李吉祯,蔚红建,付小龙,邵重斌,吴淑新,樊学忠.多硝基吡啶类化合物的合成及应用研究进展[J].化学推进剂与高分子材料,2010,8(5):32-36. |
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| 作者姓名： | 王琼 李吉祯 蔚红建 付小龙 邵重斌 吴淑新 樊学忠 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 摘 要： | 综述了2,6-二氨基-3,5-二硝基吡啶(ANPy)及其氧化物(ANPyO)、2,4,6-三氨基-3,5-二硝基吡啶(TANPy)及其氧化物(TANPyO)、2,4,6-三硝基吡啶(TNPy)及其氧化物(TNPyO)等多硝基吡啶类含能化合物的合成及应用研究进展。ANPyO的爆轰性能和安全性能与三氨基三硝基苯(TATB)接近,可作为高能钝感炸药;理论预测TANPy比TATB钝感;TNPyO具有良好的热稳定性和化学稳定性。预计这些多硝基吡啶类含能化合物在钝感炸药、低易损发射药和钝感推进剂领域中有良好的应用前景。
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| 关 键 词： | 多硝基吡啶类含能化合物 推进剂 合成 应用 |
Research Progresses on Synthesis and Application of Polynitropyridines Energetic Compounds |
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| WANG Qiong,LI Jizhen,YU Hongjian,FU Xiaolong,SHAO Chongbin,WU Shuxin,FAN Xuezhong.Research Progresses on Synthesis and Application of Polynitropyridines Energetic Compounds[J].Chemical Propellants & Polymeric Materials,2010,8(5):32-36. |
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| Authors: | WANG Qiong LI Jizhen YU Hongjian FU Xiaolong SHAO Chongbin WU Shuxin FAN Xuezhong |
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| Affiliation: | (Xi＇an Modern Chemistry Research Institute,Xi＇an 710065,China) |
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| Abstract: | The research progresses on synthesis and application of polynitropyridines energetic compounds,such as 2,6-diamino-3,5-dinitropyridine（ANPy） and its oxide（ANPyO）,2,4,6-triamino-3,5-dinitropyridine（TANPy） and its oxide（TANPyO）,2,4,6-trinitropyridine（TNPy） and its oxide（TNPyO）,etc are reviewed.ANPyO can be used as a insensitive high-energy explosive because of its near detonation and safety properties with triaminotrinitrobenzene（TATB）.It is forecast theoretically that TANPy is less sensitive than TATB.TNPyO has excellent thermal and chemical stability.It is predicted that those polynitropyridine energetic compounds have a good application prospect in the field of insensitive explosive,low vulnerable propellant and insensitive propellant. |
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| Keywords: | polynitropyridines energetic compound propellant synthesis application |
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