| 大环席夫碱配合物的合成,表征及性质研究 |
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| 引用本文： | 万博,时茜.大环席夫碱配合物的合成,表征及性质研究[J].辽宁化工,2012,41(7):647-648,651. |
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| 作者姓名： | 万博 时茜 |
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| 作者单位： | 温州大学化学与材料工程学院,浙江温州,325035 |
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| 基金项目： | 国家自然科学基金(20971101)的大力资助 |
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| 摘 要： | 设计合成了Co(Ⅱ)大环席夫碱化合物1,Co2L1(H2O)4Co2L1(H2O)2(CH3O)2·2(C14H8O4)(L1=3,7,15,19-四氮杂-25,26二羟基-11,23-二甲基-五环-二十六烷-八烯);通过红外光谱,单晶衍射对化合物的组成和结构进行表征,通过热重,分析该化合物的热稳定性.
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| 关 键 词： | 席夫碱化合物 晶体结构 热重 |
Study on Synthesis and Characterization of Macrocyclic Schiff-base Complex |
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| WAN Bo
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SHI Qian.Study on Synthesis and Characterization of Macrocyclic Schiff-base Complex[J].Liaoning Chemical Industry,2012,41(7):647-648,651. |
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| Authors: | WAN Bo SHI Qian |
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| Affiliation: | (Wenzhou University,Zhejiang Wenzhou 325035,China) |
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| Abstract: | A Co(Ⅱ) macrocyclic Schiff-base complex,Co2L1(H2O)4?Co2L1(H2O)2(CH3O)2?2(C14H8O4)(L1 = 3,7,15,19-tetraaza-25,26-dihydroxy-11,23-dimethyl-pentacyclic-26-alkane-8-alkene) was synthesized.The complex was characterized by IR spectra,and the crystal structure was determined by X-ray diffraction.The thermal stability of the complex was analyzed by the thermogravimetry. |
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| Keywords: | macrocyclic Schiff-Base complex crystal structure thermogravimetry |
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