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离子液体中硝基苯的传质特性
引用本文:陈松,陈亮,严金龙.离子液体中硝基苯的传质特性[J].辽宁化工,2009,38(12):863-864,888.
作者姓名:陈松  陈亮  严金龙
作者单位:盐城工学院应用化学研究所,江苏,盐城,224002
基金项目:江苏省高校自然科学基金(08KJD150007)盐城工学院科技基金 
摘    要:应用循环伏安法测定了离子液体中硝基苯的扩散系数。硝基苯在离子液体中电还原,其扩散系数受硝基苯、离子液体及水的相互作用影响,随内外条件变化呈现复杂的变化规律。随硝基苯浓度增加扩散系数减小;相同硝基苯浓度时,水的浓度增加扩散系数增大;随着温度升高硝基苯扩散系数增大。

关 键 词:硝基苯  离子液体    扩散系数

The Mass Transformation Characteristics of Nitrobenzene in Ionic Liquids
CHEN Song,CHEN Liang,YAN Jin-long.The Mass Transformation Characteristics of Nitrobenzene in Ionic Liquids[J].Liaoning Chemical Industry,2009,38(12):863-864,888.
Authors:CHEN Song  CHEN Liang  YAN Jin-long
Affiliation:(Institute of Applied Chemistry, Yancheng Institute of Technology, Yancheng 224002, China)
Abstract:The diffusion coefficient of nitrobenzene electrochemical reduction in EMimBF4 was investigated by cyclic voltammetry. The results show that the interaction between EMimBF4, nitrobenzene and water has complicated effect on diffusion coefficient. With increasing of nitrobenzene concentration in EMimBF4, the diffusion coefficient decreases. When nitrobenzene concentration is same, with increasing of temperature and water concentration , the diffusion coefficient increases.
Keywords:Nitrobenzene  Ionic Liquids  Water  Diffusion Coefficent
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