| 聚氧化乙烯-蒙脱土复合聚合物电解质室温电导率的研究 |
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| 引用本文： | 李冰,王继库,林海云.聚氧化乙烯-蒙脱土复合聚合物电解质室温电导率的研究[J].辽宁化工,2006,35(7):379-381,403. |
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| 作者姓名： | 李冰 王继库 林海云 |
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| 作者单位： | 沈阳化工学院材料学院,辽宁,沈阳,110142 |
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| 摘 要： | 采用溶液浇铸法对蒙脱土与聚氧乙烯、LiClO4进行复合制备了聚合物电解质膜。用X射线衍射对蒙脱土及电解质膜进行了结构表征。采用交流阻抗法对复合型电解质膜的离子电导率进行了测试。结果表明：一定量的蒙脱土可以使（PEO）16LiClO4的离子电导率提高几倍。蒙脱土对基体离子电导率提高程度的不同取决于蒙脱土的含量。
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| 关 键 词： | 聚合物电解质 嵌入型材料 PEO |
| 文章编号： | 1004-0935（2006）07-0379-04 |
| 收稿时间： | 2006-02-26 |
| 修稿时间： | 2006-02-26 |
Study on the Room Temperature Conductivity of PEO- montmorillonite Composite Polymer Electrolyte |
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| LI Bing,WANG Ji-ku,LIN Hai-yun.Study on the Room Temperature Conductivity of PEO- montmorillonite Composite Polymer Electrolyte[J].Liaoning Chemical Industry,2006,35(7):379-381,403. |
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| Authors: | LI Bing WANG Ji-ku LIN Hai-yun |
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| Affiliation: | School of Material Science, Shenyang Institute of Chemical Technology, Shenyang 110142, China |
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| Abstract: | Composite polymer electrolytes were prepared with solvent casting technique to form complex montmorillonite with LiClO_4 and PEO(polyethylene oxide). The structure of montmorillonite and electrolyte films was characterized by X-ray diffraction.The ionic conductivities were measured by AC impedance analysis.The results indicate that the addition of a certain amount of montmorillonite enhances the ionic conductivity of(PEO)_(16)LiClO_4 electrolyte by several times. The difference in enhancement of conductivity can be attributed to the difference in amount of montmorillonite in the samples. |
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| Keywords: | Polymer electrolyte Intercalation material PEO |
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