| 新型席夫碱的合成及光学性质研究 |
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| 引用本文： | 齐德强,林飘飘,倪芬芬,孔天浩.新型席夫碱的合成及光学性质研究[J].广州化工,2011(3):71-72,75. |
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| 作者姓名： | 齐德强 林飘飘 倪芬芬 孔天浩 |
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| 作者单位： | 浙江外国语学院理工学院,浙江杭州,310012 |
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| 基金项目： | 浙江省大学生科技创新活动计划(新苗人才计划)项目 |
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| 摘 要： | 以4,4＇-二氨基联苯和3-氰基苯甲醛为原料,冰醋酸作催化剂,在乙醇中反应得到一种新型的双席夫碱化合物,经核磁共振、红外光谱和元素分析表征,产物为4,4’-二（3-氰基苯基）亚甲胺基]联苯,对其紫外吸收和荧光光谱性质进行了研究。
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| 关 键 词： | 4 4＇-二氨基联苯 3-氰基苯甲醛 席夫碱 4 4’-二[（3-氰基苯基）亚甲胺基]联苯 |
Synthesis and Spectrum Properties of A Novel Schiff-base Compound |
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| QI De-qiang,LIN Piao-piao,NI Fen-fen,KONG Tian-hao.Synthesis and Spectrum Properties of A Novel Schiff-base Compound[J].GuangZhou Chemical Industry and Technology,2011(3):71-72,75. |
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| Authors: | QI De-qiang LIN Piao-piao NI Fen-fen KONG Tian-hao |
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| Affiliation: | (School of Science and Technology,Zhejiang International Studies University,Zhejiang Hangzhou 310012,China) |
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| Abstract: | A novel bis-Schiff-base named 4,4’-bis(3-cyanophenyl)iminomethyl] bipenyl derived from 4,4’-diaminobiphenyl and 3-cyanobenzaldehyde was synthesized in the presence of acetic acid in ethanol solution.The structure of the Schiff-base compound was characterized by 1H NMR,IR and element analysis.Its UV absorption spectrum and fluorescence properties were investigated. |
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| Keywords: | 4 4’-diaminobiphenyl 3-cyanobenzaldehyde Schiff-base 4 4’-bis[(3-cyanophenyl)iminomethyl] bipenyl |
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