Microwave Discharge of O2 and CO2 as a Synthetic Tool for Oxidations of Unsaturated Compounds Adsorbed on Solid Supports |
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| Authors: | Elazar Zadok Sara Rubinraut Yehuda Mazur |
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| Affiliation: | Department of Organic Chemistry, The Weizmann Institute of Science, Rehovot, Israel |
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| Abstract: | Cis and trans stilbene, styrene, 1-decene and 6-dodecene adsorbed on silica gel were reacted with oxygen atoms produced by microwave discharge of O2 and CO2. At 0°C these compounds gave mainly epoxides and carbonyl compounds as in neat liquid reactions. Below — 60°C ozonolysis products were formed; cis and trans stilbene and styrene gave benzaldehyde while 1-decene and 6-dodecene resulted mainly in ozonides. |
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