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不同氧乙基数十六烷基聚氧乙烯醚磺酸钠的界面性能
引用本文:张继超,马宝东,张永民,刘晓臣,牛金平.不同氧乙基数十六烷基聚氧乙烯醚磺酸钠的界面性能[J].日用化学工业,2011,41(2).
作者姓名:张继超  马宝东  张永民  刘晓臣  牛金平
作者单位:1. 中石化股份有限公司,胜利油田分公司,地质科学研究院,山东东营,257015
2. 中石化股份有限公司,胜利油田分公司,地质科学研究院,山东东营,257015;山东大学环境科学与工程学院,山东济南,250100
3. 中国日用化学工业研究院,山西太原,030001
摘    要:分别测定了3种不同氧乙基(EO)数的十六烷基聚氧乙烯醚磺酸钠C16EnSO(n=3,5,7)水溶液的表面张力、临界胶束浓度、界面张力、乳化能力及模拟驱油率;利用Klett光电比色仪评价了表面活性剂水溶液的乳化能力.结果显示,随着EO数的增加,C16EnSO的表面活性呈单调型变化,而界面张力、润湿力、乳化力、模拟驱油率呈类似V型变化;C16EnSO及C16EnSO水溶液与胜利孤东原油间的界面张力达到10-2mN·m-1数量级,但EO数大于7后,界面张力明显升高;界面张力越低,润湿及乳化能力越好,相应地模拟驱油率越高,但润湿及乳化能力对模拟驱油率的影响程度似乎高于界面张力.

关 键 词:十六烷基聚氧乙烯醚磺酸钠  表面活性  模拟驱油率

Interfacial performance of sodium polyethoxylated hexadecanol sulfonates with different number of EO groups
ZHANG Ji-chao,MA Bao-dong,ZHANG Yong-min,LIU Xiao-chen,NIU Jin-ping.Interfacial performance of sodium polyethoxylated hexadecanol sulfonates with different number of EO groups[J].China Surfactant Detergent & Cosmetics,2011,41(2).
Authors:ZHANG Ji-chao  MA Bao-dong  ZHANG Yong-min  LIU Xiao-chen  NIU Jin-ping
Affiliation:ZHANG Ji-chao1,MA Bao-dong1,3,ZHANG Yong-min2,LIU Xiao-chen2,NIU Jin-ping2(1.Geological Scientific Research Institute of Shengli Oil Field Corporation,SINOPEC,Dongying,Shandong 257015,China,2.Research Institute of Daily Chemical Industry,Taiyuan,Shanxi 030001,3.School of Environmental Science and Engineering,Shandong University,Jinan,Shandong 250100,China)
Abstract:Surface tension,critical micelle concentration,interfacial tension,emulsifying power and mimic oil recovery efficiency of aqueous solution of three kinds of surfactant,sodium polyethoxylated hexadecanol sulfonates with different number of EO groups(C16EnSO,n=3,5,7) were measured individually.Emulsifying power of the surfactant was evaluated using Klett photoelectric colorimeter.The results showed that:(1) as EO number of C16EnSO increased,surface activity increases accordingly towards a single direction;whi...
Keywords:sodiumpolye thoxylated hexadecanol sulfonate  surface activity  mimic oil recovery efficiency  
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