Photoelectrocatalysis reactivity of independent titania nanotubes |
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Authors: | Yibing Xie Degang Fu |
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Affiliation: | (1) School of Chemistry and Chemical Engineering, Southeast University, Nanjing, China;(2) State Key Laboratory of Bioelectronics, Southeast University, Nanjing, China |
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Abstract: | Two types of independent titania nanotube arrays with the separated tube wall structure have been fabricated by a controlled
anodization process and used for photoelectrocatalysis (PEC) applications. The photocatalysis degradation efficiency of the
organic pollutant is improved from 6.0 to 9.2% through increasing tube length and inter-tube space. The PEC degradation efficiency
is 20.4% at an applied potential of 2.885 V for titania long nanotube array. An electro-Fenton-assisted PEC reaction system
has been developed using titania long nanotube array and an iron sheet as two anodes in a parallel connection and a multiporous
carbon as one cathode. The current distribution among three functional electrodes is conducted to optimize titania PEC reaction
and electro-Fenton reaction. Accordingly, the degradation efficiency is improved from 20.4% in PEC to 60.2% in electro-Fenton-assisted
PEC, and the mineralization efficiency is also improved from 8.1 to 37.4%. The corresponding reaction rate constant of 5.19 × 10−3 min−1 is even higher than that of 3.98 × 10−3 min−1 for the sum of individual oxidation reactions of titania PEC, electro-Fenton, and anodic electrolysis. |
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