Non-woven fabric supported poly(acrylonitrile-vinyl acetate) gel electrolyte for lithium ion battery use |
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Authors: | Xiaoping Li Mumin Rao Youhao Liao Weishan Li Mengqing Xu |
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Affiliation: | (1) School of Chemistry and Environment and Key Laboratory of Electrochemical Technology on Energy Storage and Power Generation of Guangdong Higher Education Institutes, South China Normal University, Guangzhou, 510006, China; |
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Abstract: | This paper reported on a new gel polymer electrolyte (GPE) based on polyethylene (PE) non-woven fabric supported poly(acrylonitrile-vinyl
acetate) (P(AN-VAc)/PE) membrane for lithium ion battery use. The preparation and performances of the P(AN-VAc)/PE membrane
and its GPE based on 1 M LiPF6 in dimethyl carbonate/diethylene carbonate/ethylene carbonate (1:1:1 in volume) were investigated with a comparison of the
unsupported P(AN-VAc) membrane. It is found that the P(AN-VAc)/PE membrane shows better mechanical strength and pore structure
for electrolyte uptake than the P(AN-VAc) membrane, and subsequently the GPE based on P(AN-VAc)/PE exhibits higher ionic conductivity
and electrochemical stability on cathode than the GPE based on P(AN-VAc). With the support of the non-woven fabric, the ionic
conductivity of the GPE at room temperature increases from 1.4 to 3.8 mS cm−1, the oxidation decomposition potential of the GPE on a stainless steel is improved from 5.0 to 5.6 V (vs. Li/Li+). The mesocarbon microbeads (MCMB)/LiMn2O4 battery using P(AN-VAc)/PE as separator retains 94% of its initial discharge capacity after 100 cycles at C/2 rate, showing that the P(AN-VAc)/PE membrane is a possible alternative to the expensive separator for current liquid lithium
ion battery. |
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