| 糖醛酸合成方法的研究进展 |
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| 引用本文： | 来庚,张军良,郭燕文,叶彦春,杨金贤. 糖醛酸合成方法的研究进展[J]. 精细与专用化学品, 2006, 14(5): 8-10,29 |
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| 作者姓名： | 来庚 张军良 郭燕文 叶彦春 杨金贤 |
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| 作者单位： | 北京理工大学理学院有机化学教研室,北京,100081;北京理工大学理学院有机化学教研室,北京,100081;北京理工大学理学院有机化学教研室,北京,100081;北京理工大学理学院有机化学教研室,北京,100081;北京理工大学理学院有机化学教研室,北京,100081 |
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| 摘 要： | 目前糖醛酸的合成主要是以单糖为原料氧化而得。分别就糖醛酸的几种常用合成方法进行了介绍,即直接将羟甲基氧化成羧基的一步法和先将羟甲基氧化成甲酰基、再氧化成羧基的两步法。并分别讨论了几种方法的优缺点、催化剂的选择及其适用的反应条件。
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| 关 键 词： | 糖醛酸 葡萄糖 吡啶 氧化法 |
| 修稿时间： | 2005-11-01 |
Research Progress on Methods of Synthesizing Uronic Acid |
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| LAI Geng,ZHANG Jun-liang,GUO Yan-wen,YE Yan-chun,YANG Jin-xian. Research Progress on Methods of Synthesizing Uronic Acid[J]. Fine and Specialty Chemicals, 2006, 14(5): 8-10,29 |
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| Authors: | LAI Geng ZHANG Jun-liang GUO Yan-wen YE Yan-chun YANG Jin-xian |
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| Abstract: | Uronic acid can be synthesized by oxidation of monosaccharide. Several methods applied widely for synthesizing uronic acid are introduced,such as methods of one-step process and two-step process.The method of directly oxidizing the hydroxymethyl to carboxylic group is named one-step process.And the method which is firstly oxidizing hydroxymethyl to formacyl and secondly oxidizing formacyl to carboxylic group are called two-step process.Meanwhile,the advantage and shortcoming of the methods,and selection of catalyst and the appropriate reaction condition of the methods are discussed. |
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| Keywords: | uronic acid glucose pyridine oxidation process |
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