Amide-containing segmented copolymers |
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| Affiliation: | 1. State Key Lab of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China;2. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China;1. College of Materials Science and Engineering, Wuhan Textile University, Wuhan 430200, China;2. College of Science, China University of Petroleum, Beijing 102249, China;3. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, Changchun 130022, China;4. College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, China;5. College of Textiles and Clothing, Jiangnan University, Wuxi 214122, China;1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China;1. College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, PR China;2. College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 211816, PR China |
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| Abstract: | This review highlights the synthesis, physical properties, and emerging technologies of state-of-the-art segmented copolymers containing amide hydrogen bonding sites. Amide hydrogen bonding plays a crucial role in the physical properties associated with amide-containing segmented copolymers. Amide hard segments are accessible in many different forms from amorphous alkyl amides to crystalline aramids and greatly influence copolymer morphology and mechanical properties. Variations in copolymer structure allow for the fine tuning of physical properties and the ability to predict mechanical performance based upon structural modifications. This review includes various synthetic methods for producing well-defined amide-containing segmented copolymers as well as common applications. Also, the morphological and mechanical properties associated with modifications in copolymer structure are discussed. |
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| Keywords: | Segmented copolymer Hydrogen bonding Poly(amide) Thermoplastic elastomer Microphase separation |
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