| Production of Camphene by Isomerization Reaction on Sulfated ZrO2 |
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| 作者姓名： | Nora Alejandra Comelli Omar Masini Alfredo L’azaro Carrascull Esther Natalia Ponzi Marta Isabel Ponzi |
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| 作者单位： | INTEQUI(CONICET-UNSL)，Facultad de Ingenieriay Ciencias Economico Sociales，25 de Mayo 384，V.Mercedes (SL)，Argentina，INTEQUI(CONICET-UNSL)，Facultad de Ingenieriay Ciencias Economico Sociales，25 de Mayo 384，V.Mercedes (SL)，Argentina，INTEQUI(CONICET-UNSL)，Facultad de Ingenieriay Ciencias Economico Sociales，25 de Mayo 384，V.Mercedes (SL)，Argentina，INTEQUI(CONICET-UNSL)，Facultad de Ingenieriay Ciencias Economico Sociales，25 de Mayo 384，V.Mercedes (SL)，Argentina，CINDECA(CONICET-UNLP)Calle 47 N°257，1900 La Plata，Argentina |
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| 摘 要： | Abstract The kinetics of camphene production in liquid phase from α-pinene was experimentally determinedin an isothermal batch reactor.To this end,a sulfated ZrO_2 catalyst was used and the reaction studied in thetemperature range of 370-403K.By analyzing the experimental data,second reaction order for α-pinene wasfound.A kinetic model is presented which includes term for the catalyst load used.The specific rate constant at393K was 2.19×10~(-3)mol.L~(-1),min~(-1),the activation energy being 93kJ.mol~(-1).Both Vaues are within the rangeof literature results.
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| 关 键 词： | 生产工艺 莰烯 异构化反应 硫酸盐 催化剂 ZrO2 反应动力学 α-蒎烯 |
| 修稿时间： | |
Production of Camphene by Isomerization Reaction on Sulfated ZrO2 |
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| Nora Alejandra Comellia,Omar Masinia,Alfredo Lazaro Carrasculla,Esther Natalia
Ponzib and Marta Isabel Ponzia
aINTEQUI.Production of Camphene by Isomerization Reaction on Sulfated ZrO2[J].Chinese Journal of Chemical Engineering,2000,8(1):64-67. |
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| Authors: | Nora Alejandra Comellia Omar Masinia Alfredo Lazaro Carrasculla Esther Natalia
Ponzib and Marta Isabel Ponzia
aINTEQUI |
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| Abstract: | The kinetics of camphene production in liquid phase from -pinene wasexperimentally |
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| Keywords: | camphene kinetics a-pinene zirconium oxide superacid catalyst |
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