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用UV/H2O2,UV/O3,UV/H2O2/O3催化处理城市固体垃圾填埋渗出物
作者姓名:Tahir Imran QURESHI  Hong-Tae KIM  Young-Ju KIM
作者单位:Tahir Imran QURESHI,Hong-Tae KIM and Young-Ju KIMDepartment of Environmental Engineering,Department of Civil Engineering,Kyungpook National University,Taegu 702-701,Korea
摘    要:The performance of UV/H2O2, UV/O3, and UV/H2O2/O3 oxidation systems for the treatment of municipal solid-waste landfill leachate was investigated. Main objective of the experiment was to remove total organic carbon (TOC), non-biodegradable organic compounds (NBDOC) and color. In UV/H2O2 oxidation experiment, with the increase of H2O2 dosage, removal efficiencies of TOC and color along with the ratio of biochemical oxygen demand (BOD) to chemical oxygen demand (COD) of the effluent were increased and a better performance was obtained than the system H2O2 alone. In UV/H2O2 oxidation, under the optimum condition H2O2 (0.2 time), removal efficiencies of TOC and color were 78.9% and 95.5%, respectively, and BOD/COD ratio was significantly increased from 0.112 to 0.366. In UV/O3 oxidation, with the increase of O3 dosage, removal efficiencies of TOC and color along with BOD/COD ratio of the effluent were increased and a better performance was obtained than the system O3 alone. Under the optimum condition UV/O3

关 键 词:城市固体废物填埋物浸出液  紫外线-催化处理  过氧化氢  臭氧氧化
修稿时间: 

UV-Catalytic Treatment of Municipal Solid-Waste Landfill Leachate with Hydrogen Peroxide and Ozone Oxidation
Tahir Imran QURESHI,Hong-Tae KIM,Young-Ju KIM.UV-Catalytic Treatment of Municipal Solid-Waste Landfill Leachate with Hydrogen Peroxide and Ozone Oxidation[J].Chinese Journal of Chemical Engineering,2002,10(4):444-449.
Authors:Tahir Imran Qureshi  Hong-Tae KIM  Young-Ju KIM
Affiliation:Department of Environmental Engineering, Kyungpook National University,Taegu 702-701, Korea Department of Civil Engineering, Kyungpook National University,Taegu 702-701, Korea
Abstract:The performance of UV/H2O2, UV/O3, and UV/H2O2/O3 oxidation systems for the treatment of municipal solid-waste landfill leachate was investigated. Main objective of the experiment was to remove total organic carbon (TOC), non-biodegradable organic compounds (NBDOC) and color. In UV/H2O2 oxidation experiment, with the increase of H2O2 dosage, removal efficiencies of TOC and color along with the ratio of biochemical oxygen demand (BOD) to chemical oxygen demand (COD) of the effluent were increased and a better performance was obtained than the system H2O2 alone. In UV/H2O2 oxidation, under the optimum condition H2O2 (0.2 time), removal efficiencies of TOC and color were 78.9% and 95.5%, respectively, and BOD/COD ratio was significantly increased from 0.112 to 0.366. In UV/O3 oxidation, with the increase of O3 dosage, removal efficiencies of TOC and color along with BOD/COD ratio of the effluent were increased and a better performance was obtained than the system O3 alone. Under the optimum condition UV/O3 (50mg-min-1), removal efficiencies of TOC and color were 61.0% and 87.2%, respectively, and BOD/COD ratio was significantly increased from 0.112 to 0.323. In UV/H2O2/O3 system, color removal and BOD/COD ratio were improved further and TOC removal efficiency was found to be 30.4% higher than the system UV/O3 without H2O2.
Keywords:photochemical degradation  UV/ozone  UV/hydrogen peroxide  advanced oxidation process  landfill leachate  UV-reflecting reactor
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