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以弱碱性树脂去除废水中5-氨基-2-氯苯-4-磺酸和盐酸
引用本文:李长海,许振良,李春平.以弱碱性树脂去除废水中5-氨基-2-氯苯-4-磺酸和盐酸[J].中国化学工程学报,2006,14(5):696-699.
作者姓名:李长海  许振良  李春平
作者单位:[1]School of Chemical Engineering, East China University of Science & Technology.Shanghai 200237, China [2]School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China
摘    要:This research deals with an investigation of the adsorption of two acids, namely, 5-amino- 2-chlorotoluene-4-sulfonic and chlorhydric acids from their solution onto weakly basic resin. The screening of resins, kinetics, and isotherm were studied. The results indicate that the D301R is more appropriate for the removal of acids from solution. The adsorption of acids obeys Langmuir isotherm and the first-order kinetics model. Sorptive affinity of the two acids on D301R was found to be in the order of 5-amino-2-chlorotoluene-4-sulfonic acid〉 chlorhydric acid. Thermodynamic parameters for the adsorption of acids were calculated and discussed. The maximum removal of acids was observed around 97% and 76% at 25℃ for 5-amino-2-chlorotoluene-4-sulfonic acid and chlorhydric acid, respectively.

关 键 词:弱碱性树脂  废水处理  5-氨基-2-氯苯-4-磺酸  盐酸
收稿时间:2005-08-09
修稿时间:2005-08-092006-06-06

Removal of 5-Amino-2-chlorotoluene-4-sulfonic and Chlorhydric  Acids from Wastewater by Weakly Basic Resin
LIChanghai,XUZhenliang,LIChunping.Removal of 5-Amino-2-chlorotoluene-4-sulfonic and Chlorhydric  Acids from Wastewater by Weakly Basic Resin[J].Chinese Journal of Chemical Engineering,2006,14(5):696-699.
Authors:LIChanghai  XUZhenliang  LIChunping
Affiliation: School of Chemical Engineering, East China University of Science & Technology, Shanghai 200237, China   School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China 
Abstract:This research deals with an investigation of the adsorption of two acids, namely, 5-amino-2-chlorotoluene-4-sulfonic and chlorhydric acids from their solution onto weakly basic resin. The screening of resins, kinetics, and isotherm were studied. The results indicate that the D301R is more appropriate for the removal of acids from solution. The adsorption of acids obeys Langmuir isotherm and the first-order kinetics model. Sorptive affinity of the two acids on D301R was found to be in the order of 5-amino-2-chlorotoluene-4-sulfonic acid>chlorhydric acid. Thermodynamic parameters for the adsorption of acids were calculated and discussed. The maximum removal of acids was observed around 97% and 76% at 25℃ for 5-amino-2-chlorotoluene-4-sulfonic acid and chlorhydric acid, respectively.
Keywords:5-amino-2-chlorotoluene-4-sulfonic acid  chlorhydric acid  adsorption  weakly basic resin
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