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皮胶原纤维负载钦对核工业废水中铀的去除(英文)
引用本文:程远梅,孙霞,廖学品,石碧.皮胶原纤维负载钦对核工业废水中铀的去除(英文)[J].中国化学工程学报,2011,19(4):592-597.
作者姓名:程远梅  孙霞  廖学品  石碧
作者单位:1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China;2. National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China
基金项目:Supported by the National Natural Science Foundation of China (20976111); Sichuan Province Technologies R&D Program(2008GZ0026)
摘    要:Effective recovery of UO2+2 from wastewater is essential for nuclear fuel industry and related industries.In this study,a novel adsorbent was prepared by loading titanium(Ti4+) onto collagen fiber(TICF),and its physical and chemical properties as well as adsorption to UO2+2 in nuclear fuel industrial wastewater were investigated.It is found that TICF can effectively recover UO2+2 from the wastewater with excellent adsorption capacity.The adsorption capacity is 0.62 mmol·g-1 at 303 K and pH 5.0 when the initial concentration of UO2+2 is 1.50 mmol·L-1.The adsorption isotherms can be described by the Langmuir equation and the adsorption capacity increases with temperature.The effect of co-existed F on the adsorption capacity for UO2+2 is significant,which can be eliminated by adding aluminum ions as complexing agent,while the other co-existed ions in the solutions,including HCO-3,Cl-,NO-3,Ca2+,Mg2+ and Cu2+,have little effect on the adsorption capacity for UO2+2.The saturated TICF after UO2+2 adsorption can be regenerated by using 0.2 mol·L-1 nitrate(HNO-3) as desorption agent,and the TICF can be reused at least three times.Thus the TICF is a new and effective adsorbent for the recovery of UO2+2 from the wastewater.

关 键 词:collagen  fiber  titanium(Ⅳ)  adsorption  wastewater  
收稿时间:2010-11-15
修稿时间:2011-3-22  

Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber
YuanMei CHENG,Xia SUN,Xuepin LIAO,Bi SHI.Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber[J].Chinese Journal of Chemical Engineering,2011,19(4):592-597.
Authors:YuanMei CHENG  Xia SUN  Xuepin LIAO  Bi SHI
Affiliation:1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China;2. National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China
Abstract:Effective recovery of from wastewater is essential for nuclear fuel industry and related industries. In this study, a novel adsorbent was prepared by loading titanium (Ti4+) onto collagen fiber (TICF), and its physical and chemical properties as well as adsorption to in nuclear fuel industrial wastewater were investigated. It is found that TICF can effectively recover from the wastewater with excellent adsorption capacity. The adsorption capacity is 0.62 mmol•g1 at 303 K and pH 5.0 when the initial concentration of is 1.50 mmol•L1. The adsorption isotherms can be described by the Langmuir equation and the adsorption capacity increases with temperature. The effect of co-existed on the adsorption capacity for is significant, which can be eliminated by adding aluminum ions as complexing agent, while the other co-existed ions in the solutions, including , , , Ca2+, Mg2+ and Cu2+, have little effect on the adsorption capacity for . The saturated TICF after adsorption can be regenerated by using 0.2 mol•L1 nitrate (HNO3) as desorption agent, and the TICF can be reused at least three times. Thus the TICF is a new and effective adsorbent for the recovery of from the wastewater.
Keywords:collagen fiber  titanium(IV)  adsorption  wastewater
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