| 二氰基二硫纶·邻菲咯啉-5,6-二酮混配锰(Ⅱ)、铁(Ⅱ)、钴(Ⅱ)配合物的感光氧化特性 |
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| 引用本文： | 牛静,番庆才,李伟.二氰基二硫纶·邻菲咯啉-5,6-二酮混配锰(Ⅱ)、铁(Ⅱ)、钴(Ⅱ)配合物的感光氧化特性[J].化学与生物工程,2011(9):36-38. |
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| 作者姓名： | 牛静 番庆才 李伟 |
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| 作者单位： | 黄淮学院化学化工系,河南驻马店,463000 |
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| 基金项目： | 河南省教育厅自然科学研究计划项目(2011C150003) |
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| 摘 要： | 测定了二氰基二硫纶·邻菲咯啉-5,6-二酮混配锰(Ⅱ)、铁(Ⅱ)、钴(Ⅱ)配合物MLL'(M=Mn2+、Fe2+、Co2+；L=mnt2-,1,2-二氰基乙烯-1,2-二硫醇离子；L'=phen-5,6-dione,1,10-邻菲咯啉-5,6-二酮)在二甲基亚砜(DMSO)、丙酮(Acet)和氯仿(CHCl3)中的电子...
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| 关 键 词： | 1 10-邻菲咯啉-5 6-二酮 锰(Ⅱ) 铁(Ⅱ) 钴(Ⅱ) 电子光谱 感光氧化特性 |
Photooxydation Characteristics of M(mnt)(phen-5,6-dione)(M=Mn~(2+),Fe~(2+),Co~(2+)) |
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| NIU Jing,PAN Qing-cai,LI Wei.Photooxydation Characteristics of M(mnt)(phen-5,6-dione)(M=Mn~(2+),Fe~(2+),Co~(2+))[J].Chemistry & Bioengineering,2011(9):36-38. |
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| Authors: | NIU Jing PAN Qing-cai LI Wei |
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| Affiliation: | NIU Jing,PAN Qing-cai,LI Wei(Department of Chemistry and Chemical Engineering,Huanghuai University,Zhumadian 463000,China) |
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| Abstract: | The electronic absorption spectra of complexes M(mnt)(phen-5,6-dione)(M=Mn2+,Fe2+,Co2+;mnt2-=1,2-dicyano-1,2-ethylenedithiolate;phen-5,6-dione=1,10-phenanthroline-5,6-dione) in DMSO,acetone and CHCl3 were reported.The relationship between electronic spectrum absorption band and correlative transition in the molecular orbital energy level diagram of complex were investigated.The essence characteristics of interligand charge transfer transition(LL′CT) were dissected.The photooxydation characteristics of complexes of M(mnt)(phen-5,6-dione) in DMSO were ascertained. |
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| Keywords: | 1 10-phenanthroline-5 6-dione manganese(Ⅱ) ferrum(Ⅱ) cobalt(Ⅱ) electronic spectrum photooxydation characteristic |
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