| N-3-羧基水杨醛缩乙二胺Schiff碱单核镍配合物的微波辅助合成 |
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| 引用本文： | 牛永盛,李红春.N-3-羧基水杨醛缩乙二胺Schiff碱单核镍配合物的微波辅助合成[J].化学与生物工程,2011,28(2):12-13. |
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| 作者姓名： | 牛永盛 李红春 |
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| 作者单位： | 青岛农业大学化学与药学院,山东,青岛,266109 |
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| 基金项目： | 国家自然科学基金青年基金资助项目(51003051); 青岛农业大学博士启动基金资助项目(630924) |
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| 摘 要： | 以3-羧基水杨醛和乙二胺为原料,采用微波辐射辅助液相合成法合成了N-3-羧基水杨醛缩乙二胺配体;然后将该配体与四水醋酸镍络合,合成了一种新型的Schiff碱单核镍配合物.通过元素分析、红外光谱、质谱时Schiff碱配体及其镍配合物进行了表征.
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| 关 键 词： | Schiff碱 单核镍配合物 微波 乙二胺 3-羧基水杨醛 |
Microwave Assisted Synthesis of Mononuclear Nickel Complex of Schiff Base N-3-Carboxylsalicylidene-ethylenediimine |
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| NIU Yong-sheng,LI Hong-chun.Microwave Assisted Synthesis of Mononuclear Nickel Complex of Schiff Base N-3-Carboxylsalicylidene-ethylenediimine[J].Chemistry & Bioengineering,2011,28(2):12-13. |
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| Authors: | NIU Yong-sheng LI Hong-chun |
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| Affiliation: | NIU Yong-sheng,LI Hong-chun(School of Chemistry and Pharmacy,Qingdao Agricultural University,Qingdao 266109,China) |
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| Abstract: | Under microwave irradiation,a novel mononuclear nickel complex of Schiff base was synthesized by liquid phase reaction of Ni(Ac)2·4H2O with ligand N-3-carboxylsalicylidene-ethylenediimine,which was obtained from the reaction of 3-carboxylsalicylidene with ethylenediimine.The ligand and the complex were characterized by elemental analysis,IR and MS. |
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| Keywords: | Schiff base mononuclear nickel complex microwave ethylenediimine 3-carboxylsalicylidene |
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