| 以Keggin结构杂多阴离子掺杂的聚吡啶的化学合成及性能研究 |
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| 引用本文： | 徐靖,柳士忠.以Keggin结构杂多阴离子掺杂的聚吡啶的化学合成及性能研究[J].化学与生物工程,2000,17(5):7-8. |
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| 作者姓名： | 徐靖 柳士忠 |
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| 作者单位： | 1. 郧阳医学院化学教研室,湖北,十堰,442000
2. 湖北大学化学与材料科学学院,湖北,武汉,430062 |
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| 基金项目： | 中国科学院资助项目,, |
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| 摘 要： | 以12-钼磷酸和12-钨磷酸为掺杂剂,用化学方法合成了两种导电聚合物:聚吡啶/PMo12和聚吡啶/PW12,用IR、UV-Vis对聚合物进行了表征,并研究了其氧化还原特性及导电性,两种聚合物均具有较好的氧化还原可逆性,室温固体电导率分别为0.6 s·cm-1和0.5 s·cm-1.
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| 关 键 词： | 导电聚合物 聚吡啶 12-钼磷酸 12-钨磷酸 合成与性质 |
| 修稿时间： | 2000－06－12 |
Chemical Syntheses and Properties of Polypyridine Doped with Heteropolyanions with Keggin Structure |
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| XU Jing,LIU Shi-zhong.Chemical Syntheses and Properties of Polypyridine Doped with Heteropolyanions with Keggin Structure[J].Chemistry & Bioengineering,2000,17(5):7-8. |
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| Authors: | XU Jing LIU Shi-zhong |
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| Abstract: | The chemical syntheses of polypyridine by phosphomolybdic acid or phosphotungstic acid is discribed.The polymers were characterised by elemental analysis,IR,UV Vis.The electrochemical properties and conductive property of doped polymers were determined.The resulting hybrid materials present good electroactivity and conductivity. |
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| Keywords: | conductive polymer polypyridine phosphomolybdic acid phosphotungstic acid synthese and property |
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