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Origin and Conditions of Ketoacid Formation During Ozonation of Natural Organic Matter in Water
Authors:J F Gardía-Araya  J P Croué  F J Beltrán  B Legube
Affiliation:1. Laboratoire de Chimie de l'Eau et des Nuisances , ESIP , 40 av du Recteur Pineau, 86022 , Poitiers Cedex , FRANCE;2. Departamento de Ingeniería Química y Energética , Universidad de Extremadura , 06071 , Badajoz , SPAIN;3. Laboratoire de Chimie de l'Eau et des Nuisances , ESIP , 40 av du Recteur Pineau, 86022 , Poitiers Cedex , FRANCE;4. Departamento de Ingeniería Química y Energética , Universidad de Extremadura , 06071 , Badajoz , SPAIN
Abstract:The batch ozonation of some fractions of aqueous humic substances (humic, fulvic and hydrophilic acids) extracted from natural waters is studied. The reaction leads to oxidation byproducts such as low molecular aldehydes and ketoacids. Formation conditions and origin of some of them (glyoxylic, pyruvic and ketomalonic acids) regarding the extracted fraction of natural organic matter is established.
Keywords:Ozone  Ozonation Byproducts  Natural Organic Matter  Ketoacids  Humic Acids  Fulvic Adds  Hydrophilic Acids  Glyoxylic Acid  Pyruvic Acid  Ketomalonic Acids  Aldehydes
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