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PA6/POE/EAA共混体系的相态与性能的研究
引用本文:李小梅,武德珍,等.PA6/POE/EAA共混体系的相态与性能的研究[J].中国塑料,2002,16(8):27-30.
作者姓名:李小梅  武德珍
作者单位:北京化工大学高分子材料科学与工程学院 北京100029 (李小梅,武德珍),北京化工大学高分子材料科学与工程学院 北京100029(吴立峰)
摘    要:采用乙烯-1-辛烯共聚物弹性体(POE)为增韧剂、乙烯-甲基丙烯酸共聚物(EAA)作为增溶剂制备了以尼龙6(PA6)为基体的PA6/POE/EAA共混合金。详细研究了弹性体用量与共混体系的亚微观相态、力学性能和流变性能的关系。结果表明随着弹性体含量的增加,共混体系的分散相粒子尺寸大小没有明显变化,共混体系的冲击强度增加,拉伸强度和弯曲弹性模量降低。弹性体的增加使体系的熔体粘度降低,改善了体系的加工性能,但当POE增加到20%时,随着POE的增加,粘度不再下降。

关 键 词:共混体系  相态  性能  尼龙6  POE  EAA  塑料  增韧  改性

Study on Morphology and Properties of PA6/POE/EAA Blends
LI Xiao-mei,WU De-zhen,WU Li-feng.Study on Morphology and Properties of PA6/POE/EAA Blends[J].China Plastics,2002,16(8):27-30.
Authors:LI Xiao-mei  WU De-zhen  WU Li-feng
Abstract:Effects of elastomer ethylene-1-octene copolymer (POE) content on micro-morphology, mechanical and rheological properties of polyamide 6(PA6)/ethylene-1-octene copolymer (POE) blends compatibilized by EAA were studied. SEM photographs of PA6/POE/EAA blends showed that increasing POE content produced coarser breakage surface; the Izod impact strength was enhanced, and both tensile strength and bend modulus declined with the increase of POE. Rheological test demonstrated that more POE led to a lower viscosity and therefore improved processing performance. However, when POE content rose to 20%, viscosity of the alloys didn't decline at the same non-Newtonian shear rate any more.
Keywords:ethylene-1-octene copolymer  ethylene-acrylic acid copolymer  polyamide 6  alloy  blend
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