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金属催化剂在聚合物降解成炭阻燃中的研究进展
引用本文:刘彤,魏建斐,王锐.金属催化剂在聚合物降解成炭阻燃中的研究进展[J].中国塑料,2021,35(5):135-145.
作者姓名:刘彤  魏建斐  王锐
作者单位:1.北京服装学院材料设计与工程学院,北京 1000292.北京服装学院服装材料研究开发与评价北京市重点实验室,北京市纺织纳米纤维工程技术研究中心,北京 100029
基金项目:国家重点研发计划(2017YFB0309002);北京学者项目(RCQJ20303)
摘    要:介绍了抗熔滴阻燃聚合物的研究现状,综述了金属催化剂在催化聚合物降解成炭方面的应用,主要包括铁系、钼系、镍系、锌系化合物及部分稀土材料等作为催化剂在聚合物阻燃中催化成炭抗熔滴的研究现状,尤其重点阐述了铁系催化剂的主要作用。最后,对金属催化剂在聚酯抗熔滴中的应用进行了展望。

关 键 词:金属催化剂  阻燃聚合物  抗熔滴  成炭  
收稿时间:2020-07-13

Research Progress in Metal Catalysts for Degradation and Carbonization of Flame?retardant Polymer
LIU Tong,WEI Jianfei,WANG Rui.Research Progress in Metal Catalysts for Degradation and Carbonization of Flame?retardant Polymer[J].China Plastics,2021,35(5):135-145.
Authors:LIU Tong  WEI Jianfei  WANG Rui
Affiliation:1.School of Materials Design&Engineering,Beijing Institute of Fashion Technology,Beijing 100029,China2.Beijing Key Laboratory of Clothing Materials R&D and Assessment,Beijing Engineering Research Center of Textile Nano Fiber,Beijing Institute of Fashion Technology,Beijing 100029,China
Abstract:This paper reviewed the current research status of anti?dropping flame retardant polymers and introduced the app-lications of metal catalysts for catalyzing the degradation and carbonization of polymers. These metal catalysts include iron, molybdenum, nickel, zinc compounds, and some rare earth materials. The paper also reviewed the research progress in catalyzing carbon into anti?melt droplets in polymer flame retardancy, especially for the main role of iron catalysts. Finally, the application of metal catalysts for anti?melt droplets in polyester was prospected.
Keywords:metal catalyst  flame retardant polymer  anti-melt dropping  char formation  
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