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镍基单晶合金在900℃硫酸盐熔盐中的热腐蚀行为
引用本文:卢旭东,陈涛,李光瑞,郭策安,郝清伟.镍基单晶合金在900℃硫酸盐熔盐中的热腐蚀行为[J].电镀与精饰,2012,34(8):6-9.
作者姓名:卢旭东  陈涛  李光瑞  郭策安  郝清伟
作者单位:沈阳理工大学装备工程学院,辽宁沈阳,110159
摘    要:采用X-射线衍射、扫描电镜及能谱等测试手段,研究了一种镍基单晶合金在75%Na2SO4+25%K2SO4熔盐中的热腐蚀行为,该熔盐θ为900℃。结果表明,镍基单晶合金热腐蚀严重,出现严重的内硫化和内氧化;外层腐蚀产物由Al2O3、Cr2O3、Ni2Cr2O4和Co2Cr2O4相组成,内层为Al2O3和CrS;镍基单晶合金表面形成的氧化物发生碱性溶解。

关 键 词:镍基单晶合金  熔盐  热腐蚀

Hot Corrosion Behaviors of Single-crystal Ni-based Superalloy in Molten Sulfate at 900 ℃
LU Xu-dong , CHEN Tao , LI Guang-rui , GUO Ce-an , HAO Qing-wei.Hot Corrosion Behaviors of Single-crystal Ni-based Superalloy in Molten Sulfate at 900 ℃[J].Plating & Finishing,2012,34(8):6-9.
Authors:LU Xu-dong  CHEN Tao  LI Guang-rui  GUO Ce-an  HAO Qing-wei
Affiliation:(College of Equipment Engineering,Shenyang Ligong University,Shenyang 110159,China)
Abstract:The hot corrosion behaviors of single-crystal Ni-based superalloy were investigated at 900 ℃ in molten sulfate by using SEM,XRD and EDAX.The results showed that the oxidation and sulfuration of alloy were co-occured during the hot corrosion.After corrupted for 30 h,the oxide in the outer layer was consist of Al2O3,Cr2O3,Ni2Cr2O4 and Co2Cr2O4 phases,the oxide in the inner layer was identified as CrS and Al2O3 phase.And the dissolution of the oxides on the alloy surface obeys the regularity of alkaline dissolving.
Keywords:single-crystal Ni-based superalloy  molten sulfate  hot corrosion
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