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Statistical design of sustainable composites from poly(lactic acid) and grape pomace
Authors:Alison Gowman  Arturo Rodriguez-Uribe  Fantahun Defersha  Amar K Mohanty  Manjusri Misra
Affiliation:1. School of Engineering, University of Guelph, Guelph, Ontario, Canada

Department of Plant Agriculture, Bioproducts Discovery and Development Centre, University of Guelph, Guelph, Ontario, Canada;2. Department of Plant Agriculture, Bioproducts Discovery and Development Centre, University of Guelph, Guelph, Ontario, Canada;3. School of Engineering, University of Guelph, Guelph, Ontario, Canada

Abstract:Biocomposites from poly(lactic acid) (PLA) and grape pomace (GP) were created via injection molding to examine the effects of GP in a PLA matrix. To optimize the mechanical performance the biocomposites were compatibilized with maleic anhydride grafted PLA (MA-g-PLA). The objective of this work was to create a model that could accurately predict the mechanical properties of GP/PLA biocomposites. A region of feasibility for the biocomposites was determined using a statistical design of experiments. Linear regression was used to model the mechanical performance and predicted results with an error of 10% for both tensile and flexural strength and 16% for impact strength. The model was verified with a biocomposite of PLA/GP/MA-g-PLA with a ratio of 62/36/2. This biocomposite had a tensile strength, flexural modulus, and impact strength of 25.8 MPa, 40.0 MPa, and 18.4 J/m, respectively. It was found that a linear model can accurately predict the mechanical properties of PLA/GP/MA-g-PLA biocomposites.
Keywords:biopolymers and renewable polymers  compatibilization  composites  mechanical properties  surfaces and interfaces
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