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Great enhancement of mechanical features in PLA based composites containing aligned few layer graphene (FLG), the effect of FLG loading,size, and dispersion on mechanical and thermal properties
Authors:Hamza El Marouazi  Benoit van der Schueren  Damien Favier  Anaëlle Bolley  Samuel Dagorne  Thierry Dintzer  Izabela Janowska
Affiliation:1. Institut de Chimie et Procédés pour l'Énergie, l'Environnement et la Santé (ICPEES), CNRS UMR 7515, Université de Strasbourg, Strasbourg, France;2. Institute Charles Sadron (ICS), UPR 22, Université de Strasbourg, Strasbourg, France;3. Institute de Chimie de Strasbourg, CNRS UMR 7177, Université de Strasbourg, Strasbourg, France
Abstract:Four series of polylactide (PLA) based composite films containing horizontally aligned few layer graphene (FLG) flakes of high aspect ratio and adsorbed albumin are prepared. The mechanical and thermal properties varies with percentage, dispersion degree and size of FLG flakes. Great improvement up to 290% and 360% of tensile modulus and strength respectively were obtained for the composite containing high lateral size of FLG at 0.17% wt, and up to 60% and 80% for the composite with very well dispersed 0.02% wt FLG. The composites of PLA and PEG-PLLA containing very well dispersed FLG flakes at 0.07% wt are ductile showing enhancement of elongation at break up to respectively 80% and 88%. Relatively high electrical conductivity, 5 × 10−3 S/cm, is measured for PLA film charged with 3% of FLG.
Keywords:biodegradable  biomedical applications  graphene and nanotubes  mechanical properties  thermal properties
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