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Piezoelectric properties of PVDF-conjugated polymer nanofibers
Authors:Julio E Trevino  Swati Mohan  Alexandra E Salinas  Emilia Cueva  Karen Lozano
Affiliation:1. Department of Mechanical Engineering, University of Texas Rio Grande Valley, Edinburg, Texas, USA;2. Department of Chemistry, University of Texas Rio Grande Valley, Edinburg, Texas, USA;3. Department of Manufacturing Engineering, University of Texas Rio Grande Valley, Edinburg, Texas, USA
Abstract:This study presents the development and characterization of PVDF-conjugated polymer nanofiber-based systems. Five different conducting polymers (CPs) were synthesized successfully and used to create the nanofiber systems. The CPs used are polyaniline (PANI), polypyrrole (PPY), polyindole (PIN), polyanthranilic acid (PANA), and polycarbazole (PCZ). Nanofiber systems were produced utilizing the Forcespinning® technique. The nanofiber systems were developed by mechanical stretching. No electrical field or post-process poling was used in the nanofiber systems. The morphology, structure, electrochemical and piezoelectric performance was characterized. All of the nanofiber PVDF/CP systems displayed higher piezoelectric performance than the fine fiber PVDF systems. The PVDF/PPY nanofiber system displays the highest piezoelectric performance of 15.56 V. The piezoelectric performance of the PVDF/CP nanofiber systems favors potential for an attractive source of energy where highly flexible membranes could be used in power actuators, sensors and portable, and wireless devices to mention some.
Keywords:conducting polymers  electrochemistry  fibers  radical polymerization  sensors and actuators
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