Tribological mechanism improving the wear resistance of polyurethane/epoxy interpenetrating polymer network via nanodiamond hybridization |
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Authors: | Shaoling Xia Yingliang Liu Linqi Zhang Dongmei Wang Wenjun Zou Jin Peng Shaokui Cao |
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Affiliation: | 1. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, People's Republic of China;2. School of Materials Science and Engineering, Henan University of Technology, Zhengzhou, People's Republic of China |
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Abstract: | The excellent synergistic effect of physical/mechanical properties of polyurethane/epoxy (PU/EP) interpenetrating polymer network (IPN) and the validity of nanofilling have one potential to improve the wear resistance of polymeric materials. With the aim of practical application, PU/EP IPN nanocomposites are prepared with nanodiamond (ND) as a reinforcing additive. Results showed the uniform thermal stability and the excellent compatibility between PU and EP in ND‐hybridized PU/EP IPN. Simultaneously, ND particles work as crosslinked points improving the physical/mechanical properties of ND‐hybridized PU/EP IPN, especially the wear resistance. The measurement of tribological property and the scanning electron microscope indicated that the wear resistance is able to be improved a lot by the formation of IPN and by the addition of ND. Consequently, the tribological mechanism of PU/EP IPN nanocomposites comes into being. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40244. |
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Keywords: | nanoparticles nanowires and nanocrystals composites synthesis and processing surfaces and interfaces |
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