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纳米六方氮化硼负载离子液体润滑添加剂的摩擦学特性
引用本文:何忠义,贾广跃,张萌萌,晏金灿,熊丽萍,纪红兵.纳米六方氮化硼负载离子液体润滑添加剂的摩擦学特性[J].化工学报,2020,71(9):4303-4313.
作者姓名:何忠义  贾广跃  张萌萌  晏金灿  熊丽萍  纪红兵
作者单位:1.华东交通大学材料科学与工程学院, 江西 南昌 330013;2.中山大学惠州研究院,广东 惠州 516081;3.惠州学院化学与材料工程学院,广东 惠州 516007;4.中山大学化学学院, 精细化工研究院,广东省低碳化学与过程节能重点实验室,广东 广州 510275;5.广东石油化工学院化学工程学院,广东 茂名 525000
基金项目:惠州市天鹅计划领军人才项目;国家科技重大专项;广东省自然科学基金;国家自然科学基金
摘    要:制备了超声剥离的六方氮化硼负载油酸咪唑离子液体(OL-IL/h-BN)润滑添加剂,利用SEM、TEM、FTIR、TG及XRD等对其结构和形貌进行了表征。利用Zeta电位测试方法表征了其在聚乙二醇400中的分散性能,结果发现分散稳定性得到大幅提升。利用四球摩擦磨损试验机测试了摩擦学性能,结果显示减摩抗磨性能都优于h-BN。利用SEM和XPS对其磨斑表面形貌和成分进行了分析,XPS分析结果显示表面膜中含有化学吸附膜以及Fe2O3和B2O3等化学反应膜,这些膜的形成对减摩抗磨性能起到至关重要的作用。

关 键 词:离子液体  六方氮化硼  润滑添加剂  吸附  抗磨减摩  分散  
收稿时间:2020-04-13

Tribological performance of hexagonal boron nitride supported ionic liquid lubricant additives
HE Zhongyi,JIA Guangyue,ZHANG Mengmeng,YAN Jincan,XIONG Liping,JI Hongbing.Tribological performance of hexagonal boron nitride supported ionic liquid lubricant additives[J].Journal of Chemical Industry and Engineering(China),2020,71(9):4303-4313.
Authors:HE Zhongyi  JIA Guangyue  ZHANG Mengmeng  YAN Jincan  XIONG Liping  JI Hongbing
Abstract:A lubricating additive of ultrasonically exfoliated hexagonal boron nitride supported imidazole oleic acid ionic liquid (OL-IL/h-BN) was prepared, and the structure and morphology were characterized by SEM, TEM, FTIR, TG and XRD. The dispersion performance in polyethylene glycol 400 was tested by using Zeta potential test, and it was found that the dispersion stability was greatly improved. The tribological properties were tested using a four-ball machine, and the results showed that the friction-reducing and anti-wear properties were better than h-BN. The surface morphology and composition of the wear scars were analyzed by SEM and XPS. The XPS analysis results showed that the surface film contained chemical adsorption films and chemical reaction films such as Fe2O3 and B2O3. The formation of these films played an important role in reducing friction and wear resistance.
Keywords:ionic liquid  hexagonal boron nitride  lubricant  adsorption  antiwear and friction-reducing  dispersion  
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