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高性能碳基储能材料的设计、合成与应用
引用本文:王晓波,赵青山,程智年,张浩然,胡涵,王路海,吴明铂.高性能碳基储能材料的设计、合成与应用[J].化工学报,2020,71(6):2660-2677.
作者姓名:王晓波  赵青山  程智年  张浩然  胡涵  王路海  吴明铂
作者单位:1.中国石油大学(华东)化学工程学院,重质油国家重点实验室,山东 青岛 266580;2.中国石油大学(华东)石大兖矿 新能源学院,山东 青岛 266580;3.中国石油石油化工研究院,北京 100084
基金项目:国家自然科学基金;中国石油股份有限公司科学研究与技术开发项目;泰山学者项目;山东省自然科学基金
摘    要:电化学储能器件的性能很大程度上决定于其电极材料。碳材料具有来源广泛、化学稳定性好、易于调控、环境友好等优点,被广泛应用于各类能量存储系统,但仍存在能量密度低、倍率性能差等问题。本文从碳材料孔结构调控、杂原子掺杂、与金属氧化物复合三个角度,综述了构建高性能碳基储能材料的设计合成策略,介绍了其在锂/钠离子二次电池、超级电容器等领域的研究进展,对几种方法策略的优缺点进行了总结,并对未来的研究方向进行了展望。本文对高性能碳基储能电极材料的设计开发具有积极意义。

关 键 词:碳基材料  储能电极材料  孔结构调控  杂原子掺杂  金属氧化物  
收稿时间:2020-05-07
修稿时间:2020-05-18

Design,synthesis and application of high-performance carbon-based energy storage materials
WANG Xiaobo,ZHAO Qingshan,CHENG Zhinian,ZHANG Haoran,HU Han,WANG Luhai,WU Mingbo.Design,synthesis and application of high-performance carbon-based energy storage materials[J].Journal of Chemical Industry and Engineering(China),2020,71(6):2660-2677.
Authors:WANG Xiaobo  ZHAO Qingshan  CHENG Zhinian  ZHANG Haoran  HU Han  WANG Luhai  WU Mingbo
Affiliation:1.State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, Shandong, China;2.College of New Energy, China University of Petroleum (East China), Qingdao 266580, Shandong, China;3.China Petroleum and Petrochemical Research Institute, Beijing 100084, China
Abstract:The performance of electrochemical energy storage device mainly depends on the electrode materials. Carbon materials have been widely applied in various energy storage systems due to their multitudinous advantages such as wide availability, excellent chemical stability, easy to modulate, and environmental friendliness. However, traditional carbon materials still suffer from problems such as low capacity density and poor rate performance. This review focuses on the design strategies for high-performance carbon-based energy storage materials, including pore structure regulation, heteroatomic doping, and combination with metal oxides. Their applications in lithium/sodium ion secondary batteries and supercapacitors are introduced. The advantages and disadvantages of these strategies are summarized, and the future research direction is also prospected. It has positive significance for the design and development of high-performance carbon-based energy storage electrode materials.
Keywords:carbon-based materials  energy storage electrode  pore structure regulation  heteroatomic doping  metal oxide  
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