| 有机多孔聚合物CO2捕集及分离性能的研究进展 |
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| 引用本文： | 朱祥,吕文杰,胡军,汪华林,刘洪来. 有机多孔聚合物CO2捕集及分离性能的研究进展[J]. 化工学报, 2014, 65(5): 1553-1562. DOI: 10.3969/j.issn.0438-1157.2014.05.001 |
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| 作者姓名： | 朱祥 吕文杰 胡军 汪华林 刘洪来 |
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| 作者单位： | 1.华东理工大学化学系, 化学工程联合国家重点实验室, 上海 200237;2.华东理工大学国家环境保护化工过程环境风险评价与控制重点实验室, 上海 200237 |
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| 基金项目： | 国家重点基础研究发展计划项目（2013CB733501）；国家自然科学基金项目（91334203，21176066，51125032）。 |
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| 摘 要： | 有机多孔聚合物（porous organic polymers，POPs）是一类由有机构建单元连接而形成的新型多孔材料。由于其优异的物理化学稳定性以及CO2吸附能力，近年来有关POPs在CO2捕集和分离的研究成为一大研究热点。大量具有优异孔性质（比表面积和孔容）的POPs通过不同有机合成反应被成功地开发出来应用于CO2吸附分离过程。本文介绍了POPs材料的CO2捕集与分离性能的研究现状，总结了提高POPs材料CO2分离性能的合成策略，重点分析了可以通过功能化增强吸附剂与二氧化碳分子之间的相互作用，来提高材料的CO2分离能力的方法。
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| 关 键 词： | 有机多孔聚合物 二氧化碳捕集 吸附 膜分离 选择性 |
| 收稿时间： | 2014-01-07 |
| 修稿时间： | 2014-03-20 |
Progress of CO2 capture and separation by porous organic polymers |
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| ZHU Xiang,L,#,Wenjie,HU Jun,WANG Hualin,LIU Honglai. Progress of CO2 capture and separation by porous organic polymers[J]. Journal of Chemical Industry and Engineering(China), 2014, 65(5): 1553-1562. DOI: 10.3969/j.issn.0438-1157.2014.05.001 |
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| Authors: | ZHU Xiang L&# Wenjie HU Jun WANG Hualin LIU Honglai |
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| Affiliation: | 1.State Key Laboratory of Chemical Engineering, Department of Chemistry, East China University of Science and Technology, Shanghai 200237, China;2.State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai 200237, China |
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| Abstract: | Porous organic polymers (POPs), a new type of porous materials constructed by organic building blocks, have attracted attention and shown significant potential for CO2 capture and separation due to their high physicochemical stability and excellent adsorption capacity. Numerous POPs with good porosity (both surface area and pore volume) are prepared via different organic reactions. The progress of capture and separation of CO2 by POPs is reviewed. Several potential strategies like increasing isosteric heats between sorbent and CO2 molecules by chemical functionalization for enhancing CO2 separation performance are summarized. |
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| Keywords: | porous organic polymers CO2 capture adsorption membrane based separation selectivity |
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