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静电场中极板表面液膜蒸发特性研究
引用本文:常景彩,王翔,王鹏,崔琳,李军,张鑫,马春元.静电场中极板表面液膜蒸发特性研究[J].化工学报,2019,70(3):865-873.
作者姓名:常景彩  王翔  王鹏  崔琳  李军  张鑫  马春元
作者单位:1. 山东大学环境科学与工程学院,山东 青岛 2662372. 山东大学燃煤污染物减排国家工程实验室,山东 济南 2500613. 山东祥桓环保工程有限公司,山东 济南 250061
基金项目:山东省重点研发计划项目(2016CYJS10B02);国家重点研发计划项目(2017YFB0602902)
摘    要:以静电场中水分子的极化和受力特性为基础,对热干烟气中极板表面液膜内水分子输运过程进行分析。考察了电场特征、液膜物性对静态高压电场中液膜蒸发特性的影响并提出了蒸发模型;同时研究了多场(温度、速度和静电)耦合作用下液膜蒸发过程中的主导作用机制。结果表明:离子风为静态高压电场中液膜蒸发的主要动力,蒸发速率是自然蒸发的6.7倍(25 kV)。液膜蒸发为等速过程,蒸发速率与电场强度呈正相关关系;液膜加入溶质,蒸发过程受抑制,蒸发模型变为等速和降速两个过程,最终液膜表面析出溶质;流场耦合静电场作用下,液膜蒸发速率随电压升高先缓慢上升(U<20 kV)后快速上升(U>20 kV),流速和电压分别是这两阶段的主要影响因素;温度场耦合静电场作用下,蒸发速率大于单场叠加数值。研究结果为热干烟气中极板表面稳定成膜、系统水耗及空间电场中温湿度分布等问题的研究提供理论支撑。

关 键 词:蒸发  传递过程    烟道气  增湿  电极化  静电场  
收稿时间:2018-05-23
修稿时间:2018-12-21

Evaporation characteristics of water film over collecting electrode in high-voltage electrical field
Jingcai CHANG,Xiang WANG,Peng WANG,Lin CUI,Jun LI,Xin ZHANG,Chunyuan MA.Evaporation characteristics of water film over collecting electrode in high-voltage electrical field[J].Journal of Chemical Industry and Engineering(China),2019,70(3):865-873.
Authors:Jingcai CHANG  Xiang WANG  Peng WANG  Lin CUI  Jun LI  Xin ZHANG  Chunyuan MA
Affiliation:1. School of Environmental Science and Engineering, Shandong University, Qingdao 266237, Shandong, China2. National Engineering Laboratory for Coal-Fired Pollutants Emission Reduction, Shandong University, Jinan 250061, Shandong, China3. Shandong Xianghuan Environmental Protection Engineering Co., Ltd., Jinan 250061, Shandong, China
Abstract:Based on the polarization and force characteristics of water molecules in the electrostatic field, the transport process of water molecules in the liquid film on the surface of the plate in hot dry flue gas is analyzed. Besides, the effect of electrical field parameters on the evaporation characteristics and the dominant influence factors in the evaporation process under multi-field coupling effect (temperature, velocity and electrical field) were all studied. Eventually an evaporation model was proposed. The results showed that the ion wind is the main power source in the process of water film evaporation and the electric evaporation rate is 6.7 higher than the natural evaporation rate (25 kV). Water film evaporated at a constant rate and there was a positive relationship between evaporation rate and electrical field intensity. Evaporation process can be inhibited by the dissolved solute in the water film and the process was divided into two periods: constant rate period and falling rate period. The solute precipitated firstly on the water film surface. Under the coupling effect of velocity and electrical field, the evaporation rate increases slowly (U<20 kV) and then increases rapidly (U>20 kV) with increasing the voltage, velocity and voltage is the main influence factor in this two processes respectively. Under the coupling effect of temperature and electrical field, the evaporation rate is higher than the superposition of these two single fields. All these results can provide a theoretic support for the water film forming and consumption, humidity distribution in the unsaturated flue gas.
Keywords:evaporation  transport processes  film  flue gas  humidification  electric polarization  electrical field  
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