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Improved compatibility of PET/HDPE blend by using GMA grafted thermoplastic elastomer
Authors:Yang Pan  Huifang Ma  Shujie Zhou  Huixuan Zhang
Affiliation:1. School of Chemical Engineering, Changchun University of Technology , Changchun, China;2. School of Chemical Engineering, Changchun University of Technology , Changchun, China;3. Engineering Research Center of Synthetic Resin and Special Fiber, Ministry of Education, Changchun University of Technology , Changchun, China
Abstract:ABSTRACT

Herein, graft-modified ethylene-1-octene copolymer (POE-g-GMA) and styrene-butadiene-styrene triblock copolymer (SBS-g-GMA) were found to be excellent reactive compatibilizers for immiscible poly(ethylene terephthalate) (PET)/high-density polyethylene (HDPE) blends via in-situ reaction compatibilization. With increase in compatibilizer amount, uniform phase morphology was observed in all the blends. Thus, exhibiting enhanced mechanical properties, especially, the notched Izod impact strength. In comparison with SBS-g-GMA, compatibilizer POE-g-GMA demonstrated greater impact on the compatibility. The addition of 15% POE-g-GMA produced blends with best mechanical properties. Besides, both POE-g-GMA and SBS-g-GMA enhanced the melt viscosity of PET/HDPE blends.
Keywords:Compatibilizer  poly(ethylene terephthalate)  thermoplastic elastomer  high-density polyethylene  glycidyl methacrylate
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