| 水性聚酯型聚氨酯的制备及结构表征 |
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| 引用本文： | 王正辉,萧翼之. 水性聚酯型聚氨酯的制备及结构表征[J]. 聚氨酯工业, 2002, 17(3): 28-30 |
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| 作者姓名： | 王正辉 萧翼之 |
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| 作者单位： | 广州大学化学系,510405 |
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| 基金项目： | 广东省教育厅“千、百、十”人才工程资助项目，广东省环保局资助项目 |
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| 摘 要： | 由已二酸，已二醇和苯二 磺酸钠缩聚，帛得相对分子质量1825的聚酯多元醇，将自帛的聚酯多元醇与异佛二酮二异氰酸酯以及二羟甲基丙酸等单体在无有机溶剂的情况下进行预聚，最后将预聚体直接分散于水中，再经乙二胺扩链，帛得高相对分子质量，高结晶性的水基聚氨酯，用红外光谱，核磁共振氢谱，示差扫描量热以及宽角x射线衍射等手段对聚酯多元醇和聚氨酯进行了表征。
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| 关 键 词： | 无溶剂 水性聚酯型聚氨酯 制备 结构表征 |
| 修稿时间： | 2001-12-21 |
Preparation of Waterbased Polyurethane and Characterization |
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| Wang ZhengHui Xiao Yizi. Preparation of Waterbased Polyurethane and Characterization[J]. Polyurethane Industry, 2002, 17(3): 28-30 |
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| Authors: | Wang ZhengHui Xiao Yizi |
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| Abstract: | Polyol having a molecular weight of 1825 was prepared with the reaction of 5-Sulfoisophthalic acid monosodium salt,adipic acid and 1,6-dexanediol.A prepolymer was prepared by reacting the obtained polyol with isophorone diisocyanate,1,4-butanediol and 2,2-dimethylolpropionic acid.The prepolymer was dispersed under vigorous agitation by adding water and extended by adding ethylenediamine.Finally the waterbased polyurethane having high molecular weight and white paste-like was obtained.The obtained polyol and polyurethane were characterized by means of IR spectra, 1H NMR spectra,DSC and WAXD. |
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| Keywords: | polyo1 waterbased polyurethane solvent-free |
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