聚脲弹性体材料耐磨性能的探讨

由不同二元醇与二异氰酸酯合成不同NCO含量的半预聚体(A组分)与端氨基聚醚、胺扩链剂等原料组成的R组分经喷涂设备喷涂成型聚脲弹性体。讨论了在不同摩擦工况下NCO含量、异氰酸酯指数、预聚物类型、耐磨助剂等对聚脲弹性体耐磨性能的影响。结果表明,不同NCO含量在不同摩擦工况下对聚脲耐磨性能的影响不同,干摩擦工况下NCO含量越高,耐磨性能越佳,湿摩擦工况下则是NCO质量分数为15%耐磨性最佳,异氰酸酯指数对聚脲耐磨性能的影响较小,使用聚四氢呋喃二元醇、TDI预聚物和耐磨助剂,可提高不同摩擦工况下聚脲的耐磨性能。

Research in Polyurea Elastomer Material Abrasion Resistance

The spraying polyurea elastomer system was synthetized by A component and R component. The A component was a kind of quasi-prepolymer with different NCO content, synthesized by polyether diol and isocya- hate. The R component was composed of amino terminated polyether, amine extender and other additives. The in- fluence on abrasion performance under different wear conditions was discussed, such as different NCO content, iso- cyanate index, type of prepolymer and different wearable additives. The result was that different NCO content had different wear influence under different wear conditions. With the NCO content of the prepolymer increase, the bet- ter abrasion resistance the polyurea had under dry wear condition. The abrasion performance was the best when NCO content was 15% under wet wear condition. The isocyanate index had a few effects on the abrasion perform- ance. The application of polytetrahydrofuran diol, TDI perpolymer and wearable additives could improve the abra- sion resistance of polyurea under different wear conditions.