| 过氧化氢蒎烷对丁苯橡胶聚合的影响 |
| |
| 引用本文： | 王志勇,高增亮.过氧化氢蒎烷对丁苯橡胶聚合的影响[J].合成橡胶工业,2001,24(3):133-135. |
| |
| 作者姓名： | 王志勇 高增亮 |
| |
| 作者单位： | 齐鲁石油化工股份有限公司橡胶厂, |
| |
| 摘 要： | 研究了过氧化氢蒎烷（PHP）对丁苯橡胶聚合的影响，与过氧化氢二异丙苯（DIP）引发聚合的对比结果表明，PHP的催化活性要比DIP的高，同样纯度的引发剂，PHP质量分数的DIP的54％时二者具有相同的引发效果。而且对所制备胶乳性能的影响相近。用PHP制得的SBR1502橡胶的相对分子质量分布和物理机械性能与用DIP制备的接近，PHP与DIP混合引发剂不影响聚合速率。
|
| 关 键 词： | 丁苯橡胶 过氧化氢蒎烷 过氧化氢二异丙苯 聚合速率 相对分子质量分布 物理机械性能 |
| 文章编号： | 1000-1255(2001)03-0133-03 |
Effect of pinane hydroperoxide on the polymerization of SBR 1502 |
| |
| Wang Zhiyong,Gao Zengliang.Effect of pinane hydroperoxide on the polymerization of SBR 1502[J].China Synthetic Rubber Industry,2001,24(3):133-135. |
| |
| Authors: | Wang Zhiyong Gao Zengliang |
| |
| Abstract: | The effect of pinane hydroperoxide (PHP) on the polymerization of SBR 1502 was studied. The results showed that PHP had higher catalytic activity than that of diisopropylbenzene hydroperoxide(DIP), and 54% (mass fraction) PHP had the same initiation effect compared with that of 100% DIP. The effect of PHP on properties of SBR latex was similar to DIP. The Mw/Mn and properties of SBR 1502 manufactured by PHP and DIP were approximate. The mixture of PHP and DIP had no influence on polymerization rate. |
| |
| Keywords: | styrene - butadiene rubber pinane hydroperoxide diisopropylbenzene hydroperoxide polymerization rate relative molecular mass distribution mechanical property |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
