| 硅橡胶硫化体系研究进展 |
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| 引用本文： | 王明英,王健,杜思辰,卢佳,王红红,赵才德,于家成,刁 屾.硅橡胶硫化体系研究进展[J].合成橡胶工业,2022,0(3):244-252. |
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| 作者姓名： | 王明英 王健 杜思辰 卢佳 王红红 赵才德 于家成 刁 屾 |
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| 作者单位： | 烟台大学 化学化工学院，山东 烟台 264005 |
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| 摘 要： | 从传统硫化体系的优化和新型硫化体系的开发两方面系统综述了硅橡胶硫化体系的研究进展，分析了有机过氧化物硫化体系的优缺点、催化剂和抑制剂对硅氢加成硫化体系的影响，以及交联剂和催化剂对官能团缩合硫化体系的影响，简要介绍了包括辐射引发硫化体系、光引发硫化体系、基于点击化学的硫化体系和可逆共价（非共价）硫化体系等在内的新型硫化体系，最后对硅橡胶硫化体系未来的发展方向提出了建议。
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| 关 键 词： | 硅橡胶 传统硫化体系 新型硫化体系 硅氢加成反应 综述 |
Research advance in curing system of silicone rubber |
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| WANG Ming-ying,WANG Jian,DU Si-chen,LU Jia,WANG Hong-hong,ZHAO Cai-de,YU Jia-cheng,DIAO Shen.Research advance in curing system of silicone rubber[J].China Synthetic Rubber Industry,2022,0(3):244-252. |
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| Authors: | WANG Ming-ying WANG Jian DU Si-chen LU Jia WANG Hong-hong ZHAO Cai-de YU Jia-cheng DIAO Shen |
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| Affiliation: | College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, China |
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| Abstract: | Recent research progress in curing system of silicone rubber was reviewed from the optimization of traditional vulcanization system and the development of new vulcanization system with 53 references. The advantages and disadvantages of organic peroxide curing systems, the effect of the catalysts and inhibitors on hydrosilylation curing systems, and the effect of the crosslinking agents and catalysts on functional group condensation curing systems were analyzed, and the new curing systems including radiation-induced curing systems, photoinitiated curing systems, curing systems based on click chemistry, and reversible covalent (non-covalent) curing systems were briefly introduced. Finally, some suggestions on the future development of silicone rubber curing system were also put forward. |
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| Keywords: | silicone rubber traditional curing system new curing system hydrosilylation review |
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